Triethylsulfonium iodide

Base Information

• Chemical Name: Triethylsulfonium iodide
• CAS No.: 1829-92-1
• Molecular Formula: C6H15 S . I
• Molecular Weight: 246.156
• Hs Code.: 2930909090
• European Community (EC) Number: 217-383-7
• NSC Number: 36719
• DSSTox Substance ID: DTXSID10939655
• Mol file: 1829-92-1.mol

Synonyms:Triethylsulfonium iodide;1829-92-1;triethylsulfanium iodide;triethylsulfanium;iodide;Sulfonium, triethyl-, iodide;Sulfonium, triethyl-, iodide (1:1);Triethylsulphonium iodide;EINECS 217-383-7;SCHEMBL394054;C6H15S.I;DTXSID10939655;C6-H15-S.I;NSC36719;MFCD00051867;NSC 36719;NSC-36719;AKOS003242567;AS-62027;J-011712

Chemical Property of Triethylsulfonium iodide

Chemical Property:

• Melting Point: 147-148°C
• PSA: 25.30000
• LogP: -1.33160
• Sensitive.: Light Sensitive
• Water Solubility.: It is soluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 245.99392
• Heavy Atom Count: 8
• Complexity: 25.7

Purity/Quality:

98%,99%, ^*data from raw suppliers

Triethylsulfonium iodide 97% ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[S+](CC)CC.[I-]
• Uses: Triethylsulfonium iodide is used as an ethylidene-transfer reagent. It is used as a pharmaceutical intermediate.

Technology Process of Triethylsulfonium iodide

There total 13 articles about Triethylsulfonium iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

triethyl trithiophosphite (688-62-0) + benzyl bromide (100-39-0) → ethyl bromide (74-96-4) + triethylsulfonium iodide (1829-92-1) + Benzyl-phosphonotrithioic acid diethyl ester (116393-11-4)

Guidance literature:

at 20 ℃; for 4320h;

DOI:10.1007/BF00960147

Reference yield:

diethyl sulphide (352-93-2) + acetyl iodide (507-02-8) → ethyl thioacetate (625-60-5) + triethylsulfonium iodide (1829-92-1)

Guidance literature:

at 25 ℃; unter Lichtausschluss;

Reference yield:

diethyl sulphide (352-93-2) + ethyl iodide (75-03-6) → triethylsulfonium iodide (1829-92-1)

Guidance literature:

upstream raw materials:

diethyl sulphide

acetyl iodide

methyldiethylsulfonium iodide

Diethyl disulfide

Downstream raw materials:

diethyl sulphide

ethyl p-tolyl sulfone

triethylsulfonium bis(trifluoromethylsulfonyl)imide

(2R^*,3S^*)-2-(2,4-Difluorophenyl)-3-methyl-2-<(1H-1,2,4-triazol-1-yl)methyl>oxirane

Refernces

• 1、 Paulsson, Helene,Hagfeldt, Anders,Kloo, Lars. "Molten and Solid Trialkylsulfonium Iodides and Their Polyiodides as Electrolytes in Dye-Sensitized Nanocrystalline Solar Cells". . p. 13665 - 13670. Retrieved 2007/10/03.