1-Ethyl-3-p-tolyltriazene

Base Information

• Chemical Name: 1-Ethyl-3-p-tolyltriazene
• CAS No.: 50707-40-9
• Molecular Formula: C9H13 N3
• Molecular Weight: 163.222
• Hs Code.: 2928000090
• NSC Number: 146446
• UNII: 7073MFT1NZ
• DSSTox Substance ID: DTXSID10198760
• Nikkaji Number: J208.484H
• Mol file: 50707-40-9.mol

Synonyms:1-Ethyl-3-p-tolyltriazene;50707-40-9;Triazene, 1-ethyl-3-(p-tolyl)-;1-Triazene, 1-ethyl-3-(4-methylphenyl)-;N-(ethyldiazenyl)-4-methylaniline;1-Ethyl-3-(p-tolyl)triazene;7073MFT1NZ;NSC-146446;NSC 146446;NSC146446;WLN: 2NUNMR D1;3-Ethyl-1-p-tolyltriazene;UNII-7073MFT1NZ;1-Triazene, 1-ethyl-3-(4-methylphenyl)- (9CI);SCHEMBL1278595;SCHEMBL9870488;DTXSID10198760;BPOZIJBDYFHEJR-UHFFFAOYSA-N;(E)-3-ethyl-1-p-tolyltriaz-1-ene;E0292;FT-0639931;1-ETHYL-3-(4-METHYLPHENYL)-1-TRIAZENE;(1E)-3-Ethyl-1-(4-methylphenyl)-1-triazene #

Chemical Property of 1-Ethyl-3-p-tolyltriazene

Chemical Property:

• Vapor Pressure: 0.0518mmHg at 25°C
• Melting Point: 35 °C
• Refractive Index: 1.4800 (estimate)
• Boiling Point: 234.8°C at 760 mmHg
• Flash Point: 95.8°C
• PSA: 36.75000
• Density: 1.01g/cm³
• LogP: 2.99410
• XLogP3: 3
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 163.110947427
• Heavy Atom Count: 12
• Complexity: 137

Purity/Quality:

98%,99%, ^*data from raw suppliers

1-ETHYL-3-P-TOLYLTRIAZENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCN=NNC1=CC=C(C=C1)C

Technology Process of 1-Ethyl-3-p-tolyltriazene

There total 3 articles about 1-Ethyl-3-p-tolyltriazene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-methylbenzenediazonium tetrafluoroborate (459-44-9) + ethylamine (75-04-7,85404-22-4) → C9H13N3 (50707-40-9)

Guidance literature:

With sodium carbonate; In N,N-dimethyl-formamide; at -15 ℃;

Reference yield:

p-toluidine (106-49-0,12221-03-3) + ethylamine (75-04-7,85404-22-4) → C9H13N3 (50707-40-9)

Guidance literature:

p-toluidine; With hydrogenchloride; sodium nitrite; In water; for 0.25h; Cooling with ice;

ethylamine; With sodium carbonate; In water; at 20 ℃; for 0.333333h;

DOI:10.1055/s-0032-1316557

Reference yield:

→ C9H13N3 (50707-40-9)

Guidance literature:

Aus Ethylamin u. p-Tolyldiazoniumtetrafluoroborat (CH3-C6H4-N2+ BF4-);

upstream raw materials:

4-methylbenzenediazonium tetrafluoroborate

ethylamine

p-toluidine

Downstream raw materials:

para-thiocresol

p-toluidine

Ethyl 2-phenylethanoate

(6R)-7t-((R)-2-tert-butoxycarbonylamino-2-phenyl-acetylamino)-3-ethoxy-8-oxo-(6rH)-5-thia-1-aza-bicyclo[4.2.0]oct-2-ene-2-carboxylic acid benzhydryl ester

Refernces

• 1、 Laila, Abdulhameed A. R.. "STRUCTURAL EFFECT ON THE MECHANISTIC PATHWAY OF THE DECOMPOSITION OF 3-ALKYL-1-ARYLTRIAZENES: A KINETIC STUDY". . p. 453 - 456. Retrieved 2007/10/02.