5,10,15,20-TETRAKIS(4-HYDROXYPHENYL)-21H,23H-PORPHINE

Base Information

• Chemical Name: 5,10,15,20-TETRAKIS(4-HYDROXYPHENYL)-21H,23H-PORPHINE
• CAS No.: 51094-17-8
• Molecular Formula: C44H30N4O4
• Molecular Weight: 678.747
• Mol file: 51094-17-8.mol

Synonyms:5,10,15,20-Tetra(4-hydroxyphenyl)-21H,23H-porphine;5,10,15,20-Tetra(4-hydroxyphenyl)porphyrin;5,10,15,20-Tetra(p-hydroxyphenyl)porphine;5,10,15,20-Tetra(p-hydroxyphenyl)porphyrin;5,10,15,20-Tetrakis(4-hydroxyphenyl)-21H,23H-porphine;5,10,15,20-Tetrakis(4-hydroxyphenyl)-21H,23H-porphyrin;5,10,15,20-Tetrakis(4-hydroxyphenyl)porphine;5,10,15,20-Tetrakis(4-hydroxyphenyl)porphyrin;5,10,15,20-Tetrakis(4'-hydroxyphenyl)porphine;5,10,15,20-Tetrakis(p-hydroxyphenyl)porphine;5,10,15,20-Tetrakis(p-hydroxyphenyl)porphyrin;HK 7;HK 7 (porphinederivative);Mesotetrakis(4-hydroxyphenyl)porphyrin;Tetra(p-hydroxyphenyl)porphyrin;Tetrakis(4-hydroxyphenyl)porphyrin;Tetrakis(p-hydroxyphenyl)porphyrin;meso-5,10,15,20-Tetra-(4-hydroxyphenyl)porphyrin;meso-Tetra(4-hydroxyphenyl)porphine;meso-Tetra(4-hydroxyphenyl)porphyrin;meso-Tetra(p-hydroxyphenyl)porphyrin;meso-Tetrakis(4-hydroxyphenyl)porphine;meso-Tetrakis(4-hydroxyphenyl)porphyrin;meso-Tetrakis(p-hydroxyphenyl)porphyrin;a,b,g,d-Tetrakis(4-hydroxyphenyl)porphine;

Chemical Property of 5,10,15,20-TETRAKIS(4-HYDROXYPHENYL)-21H,23H-PORPHINE

Chemical Property:

• Melting Point: >300 °C(lit.)
• Refractive Index: 1.746
• PSA: 137.22000
• Density: 1.402 g/cm³
• LogP: 5.68860
• Storage Temp.: room temp

Purity/Quality:

98%,99%, ^*data from raw suppliers

meso-Tetra(p-hydroxyphenyl)porphine ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 34-37
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Uses: meso-Tetra(p-hydroxyphenyl)porphine is a porphyrin derivative used for research.

Technology Process of 5,10,15,20-TETRAKIS(4-HYDROXYPHENYL)-21H,23H-PORPHINE

There total 17 articles about 5,10,15,20-TETRAKIS(4-HYDROXYPHENYL)-21H,23H-PORPHINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

5,10,15,20-tetrakis(p-acetoxyphenyl)porphyrin (57450-61-0) → 5,10,15,20-tetrakis(4'-hydroxyphenyl)porphyrin (51094-17-8)

Guidance literature:

With hydrogenchloride; In ethanol; water; for 1h; Reflux;

DOI:10.1016/j.dyepig.2012.09.011

Reference yield: 100.0%

5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin (22112-78-3) → 5,10,15,20-tetrakis(4'-hydroxyphenyl)porphyrin (51094-17-8)

Guidance literature:

With pyridine; hydrogenchloride; In water; at 290 ℃; for 3h;

DOI:10.1142/S1088424617500109

Reference yield: 72.0%

pyrrole (109-97-7,30604-81-0) + 4-hydroxy-benzaldehyde (123-08-0,65581-83-1) → 5,10,15,20-tetrakis(4'-hydroxyphenyl)porphyrin (51094-17-8)

Guidance literature:

With toluene-4-sulfonic acid; In N,N-dimethyl-formamide;

DOI:10.1142/S1088424619500093

upstream raw materials:

pyrrolidine

4-hydroxy-benzaldehyde

pyrrole

tetrakis(4-aminophenyl)porphyrin

Downstream raw materials:

meso-tetra(4-hydroxyphenyl)porphyrin-Cu(II)

5,10,15,20-tetrakis(4-carboxymethyloxyphenyl)-21H,23H-porphine

5,10,15,20-tetrakis(4-octadecyloxyphenyl)-21H,23H-porphyrin

Refernces

• 1、 Eslami, Abbas,Gholamrezapor, Ensieh. "Photocatalytic degradation of methylene blue in aqueous solution by magnetic ZnMn2O4@copper porphyrin nanocomposite". . . Retrieved 2021.
• 2、 Kadhim, Alaa,McKenzie, Luke K.,Bryant, Helen E.,Twyman, Lance James. "Synthesis and Aggregation of a Porphyrin-Cored Hyperbranched Polyglycidol and Its Application as a Macromolecular Photosensitizer for Photodynamic Therapy". . p. 1132 - 1139. Retrieved 2019.
• 3、 Ol'ga, Akopova,Sergey, Zdanovich,Ol'ga, Zemtsova,Nadejda, Usol'tseva. "The prognosis of columnar mesomorphism and experimental data for a new series of porphin derivatives". . p. 611 - 623. Retrieved 2001.
• 4、 Gao, Yuzhou,Hou, Chunxi,Zhou, Lipeng,Zhang, Dongmei,Zhang, Chunqiu,Miao, Lu,Wang, Liang,Dong, Zeyuan,Luo, Quan,Liu, Junqiu. "A dual enzyme microgel with high antioxidant ability based on engineered seleno-ferritin and artificial superoxide dismutase". . p. 808 - 816. Retrieved 2013.
• 5、 Zhu, Mingshan,Han, Ming,Du, Yukou,Yang, Ping,Wang, Xiaomei. "The synthesis, light-harvesting, and photocatalysis of naphthylporphyrin-functionalized platinum nanocomposites". . p. 81 - 86. Retrieved 2010.
• 6、 Hou, Zhanyao,Dehaen, Wim,Lyskawa, Jo?l,Woisel, Patrice,Hoogenboom, Richard. "A supramolecular miktoarm star polymer based on porphyrin metal complexation in water". . p. 8423 - 8426. Retrieved 2017.
• 7、 Lu, Guifen,Zhang, Xiufeng,Cai, Xu,Fang, Yuanyuan,Zhu, Min,Zhu, Weihua,Ou, Zhongping,Kadish, Karl M.. "Synthesis, structural characterization and protonation/deprotonation of hydroxyl-substituted free-base tetraphenylporphyrins in nonaqueous media". . p. 941 - 953. Retrieved 2013.
• 8、 Zhang, Fengyuan,Ma, Chen,Jiao, Zhijuan,Mu, Shuai,Zhang, Yida,Liu, Xiaoyan,Zhang, Haixia. "A NIR Turn-on Fluorescent Sensor For Detection of Chloride Ions in vitro and in vivo". . . Retrieved 2020.
• 9、 Wang, Yunpu,Wang, Rongming. "Synthesis and Electrical Conductive Properties of Polymeric Metalloporphyrins". . p. 1517 - 1518. Retrieved 1992.
• 10、 Majumder, Rini,Roy, Snigdha,Okamoto, Kentaro,Nagao, Satoshi,Matsuo, Takashi,Parui, Partha Pratim. "Porphyrin-Based Probe for Simultaneous Detection of Interface Acidity and Polarity during Lipid-Phase Transition of Vesicles". . p. 426 - 434. Retrieved 2020.