CID 15093635

Base Information

• Chemical Name: CID 15093635
• CAS No.: 692-74-0
• Molecular Formula: C2F2O4
• Molecular Weight: 126.016
• DSSTox Substance ID: DTXSID40568114
• Nikkaji Number: J375.176G
• Wikidata: Q82454275
• Mol file: 692-74-0.mol

Synonyms:692-74-0;Bis(fluoroformyl)-peroxide;bis(fluorocarbonyl) peroxide;SCHEMBL11744205;DTXSID40568114;carbonofluoridoyloxy carbonofluoridate

Chemical Property of CID 15093635

Chemical Property:

• Vapor Pressure: 69.8mmHg at 25°C
• Boiling Point: 85.3°C at 760 mmHg
• Flash Point: 6.5°C
• PSA: 52.60000
• Density: 1.586g/cm³
• LogP: 1.11360
• XLogP3: 1.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 3
• Exact Mass: 125.97646480
• Heavy Atom Count: 8
• Complexity: 96.6

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=O)(OOC(=O)F)F

Technology Process of CID 15093635

There total 5 articles about CID 15093635 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

oxalyl difluoride (359-40-0) + carbon monoxide (201230-82-2) + trifluoroacetic anhydride (407-25-0) → Carbonyl fluoride (353-50-4) + trifluoroacetyl fluoride (354-34-7) + bis(trifluoromethyl)peroxide (927-84-4) + carbon dioxide (124-38-9,18923-20-1) + bis(fluoroformyl)peroxide (692-74-0) + carbonofluoridoylperoxy trifluoromethyl carbonate (1174457-95-4)

Guidance literature:

With oxygen; at -50.16 ℃; Photolysis;

DOI:10.1016/j.jfluchem.2012.05.020

Reference yield:

carbon monoxide (201230-82-2) → oxalyl difluoride (359-40-0) + bis(fluoroformyl)peroxide (692-74-0)

Guidance literature:

With dioxygenyl tetrafluoroborate; at -60 ℃;

DOI:10.1016/S0022-1139(01)00512-7

Reference yield:

oxalyl difluoride (359-40-0) → Carbonyl fluoride (353-50-4) + bis(fluoroformyl)peroxide (692-74-0) + bis(fluorocarbonyl)peroxide + bis(fluoroformyl)trioxide (177036-05-4)

Guidance literature:

With oxygen; at 24.9 ℃; for 0.25h; under 760 Torr; Product distribution; Mechanism; Quantum yield; Irradiation; kinetics, var. of bath gas, pressure;

upstream raw materials:

oxalyl difluoride

carbon monoxide

difluoroether

oxygen

Downstream raw materials:

Carbonyl fluoride

carbon dioxide

oxygen

Bis-(difluor-fluoroxy-methyl)-peroxid

Refernces

• 1、 Pernice,Willner,Eujen. "The reaction of dioxygenyl salts with 13CO Formation of F13C(O)13C(O)F". . p. 277 - 281. Retrieved 2007/10/03.