(Chloroacetoxy)triphenylstannane

Base Information

• Chemical Name: (Chloroacetoxy)triphenylstannane
• CAS No.: 7094-94-2
• Molecular Formula: C20H18ClO2Sn
• Molecular Weight: 443.517
• European Community (EC) Number: 230-401-8
• UNII: M9JNR7DSX1
• DSSTox Substance ID: DTXSID10221168
• Wikidata: Q27896331
• Mol file: 7094-94-2.mol

Synonyms:(Chloroacetoxy)triphenylstannane;triphenyltin chloroacetate;7094-94-2;M9JNR7DSX1;EINECS 230-401-8;UNII-M9JNR7DSX1;DTXSID10221168;NS00045140;ACETIC ACID, 2-CHLORO-, TRIPHENYLSTANNYL ESTER;Q27896331

Chemical Property of (Chloroacetoxy)triphenylstannane

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 40.13000
• Density: g/cm³
• LogP: 2.25160
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 6
• Exact Mass: 443.993910
• Heavy Atom Count: 24
• Complexity: 351

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Sn](C2=CC=CC=C2)(C3=CC=CC=C3)OC(=O)CCl

Technology Process of (Chloroacetoxy)triphenylstannane

There total 3 articles about (Chloroacetoxy)triphenylstannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

sodium methylate (124-41-4) + triphenyltin chloride (639-58-7) + chloroacetic acid (79-11-8) → (C6H5)3SnOCOCH2Cl (7094-94-2)

Guidance literature:

In methanol; under dry nitrogen atmosphere; reaction of (C6H5)3SnCl (10 mmol) and CH3ONa(10 mmol) at 0°C; addn. a soln. of CH2ClCOOH (10 mmol) in methanol to the formed (C6H5)3SnOCH3 soln.; stirring for 2 h at the same temperature; filtn.; concn. of the solvent under reduced pressure; recrystallization from chloroform;

Reference yield:

triphenyl(4-t-butylphenoxo)tin(IV) (159113-64-1) → triphenyyltin(IV) chloroacetate (7094-94-2)

Guidance literature:

With chloroacetic acid; In benzene; mixt. refluxed, resulting solid washed with petroleum ether; resulting solid washed with petroleum ether, dried under reduced pressure, elem. anal.;

Reference yield:

{2-HOC5H4NCH2C(O)OH}Cl + triphenyltin(IV) hydroxide (76-87-9) → triphenyyltin(IV) chloroacetate (7094-94-2)

Guidance literature:

In methanol; slow evapn.;

DOI:10.1016/0022-328X(89)85138-1

upstream raw materials:

triphenyltin(IV) hydroxide

triphenyl(4-t-butylphenoxo)tin(IV)

sodium methylate

triphenyltin chloride

Refernces