Methanol, tris (p-nitrophenyl)-

Base Information

• Chemical Name: Methanol, tris (p-nitrophenyl)-
• CAS No.: 596-48-5
• Molecular Formula: C19H13 N3 O7
• Molecular Weight: 395.328
• Mol file: 596-48-5.mol

Synonyms:Methanol,tris(p-nitrophenyl)- (6CI,7CI,8CI); 4,4',4''-Trinitrotriphenylmethanol; NSC87329; Tri-p-nitrophenylcarbinol; Tris(p-nitrophenyl)methanol

Chemical Property of Methanol, tris (p-nitrophenyl)-

Chemical Property:

• Vapor Pressure: 3.71E-17mmHg at 25°C
• Refractive Index: 1.5900 (estimate)
• Boiling Point: 638.1°Cat760mmHg
• Flash Point: 255.8°C
• PSA: 157.69000
• Density: 1.487g/cm³
• LogP: 5.26500

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methanol, tris (p-nitrophenyl)-

There total 10 articles about Methanol, tris (p-nitrophenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

1,1',1''-methylidynetris(4-nitro-benzene) (603-49-6) → tris(p-nitrophenyl)carbinol (596-48-5)

Guidance literature:

With lithium hydroxide; 18-crown-6 ether; oxygen; In 1,2-dimethoxyethane; at 20 ℃; for 1.5h;

DOI:10.1007/BF00957947

Reference yield:

1,1',1''-methylidynetris(4-nitro-benzene) (603-49-6) → 4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + tris(p-nitrophenyl)carbinol (596-48-5) + 4,4',4''-trinitro-trityl hydroperoxide

Guidance literature:

DOI:10.1021/ja01614a057

Reference yield:

→ tris(p-nitrophenyl)carbinol (596-48-5)

Guidance literature:

With chromic acid; acetic acid; at 100 ℃;

upstream raw materials:

1,1',1''-methylidynetris(4-nitro-benzene)

sodium ethanolate

benzene

dihydrogen peroxide

Downstream raw materials:

4-nitro-phenol

4,4'-dinitrobenzophenone

4-nitro-benzoic acid

bis-(4,4',4''-trinitro-trityl)-peroxide

Refernces

• 1、 Beletskaya, I. P.,Grinfel'd, A. A.,Artamkina, G. A.. "OXIDATION OF TRIS(p-NITROPHENYL)METHANE BY OXYGEN IN THE PRESENCE OF KOH IN DIMETHOXYETHANE". . p. 2367. Retrieved 2007/10/02.