Sodium tetrachloroaluminate

Base Information

• Chemical Name: Sodium tetrachloroaluminate
• CAS No.: 7784-16-9
• Molecular Formula: AlCl4Na
• Molecular Weight: 191.783
• European Community (EC) Number: 232-050-6
• Wikidata: Q8010655
• Wikipedia: Sodium tetrachloroaluminate
• Mol file: 7784-16-9.mol

Synonyms:Sodium tetrachloroaluminate;7784-16-9;Sodium tetrachloroalumanuide;sodium;tetrachloroalumanuide;ALUMINUM SODIUM CHLORIDE;NaAlCl4;sodiumtetrachloroaluminate;Sodium aluminum tetrachloride;Sodium tetrachloroaluminate, 98%;MFCD00050361;AKOS025213762;Q8010655;Sodium tetrachloroaluminate, anhydrous, powder, 99.99% trace metals basis

Chemical Property of Sodium tetrachloroaluminate

Chemical Property:

• Melting Point: 185 °C(lit.)
• PSA: 0.00000
• Density: 2.01 g/mL at 25 °C(lit.)
• LogP: 2.75800
• Sensitive.: Moisture Sensitive
• Water Solubility.: Soluble in water
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 191.843768
• Heavy Atom Count: 6
• Complexity: 19.1

Purity/Quality:

99% ^*data from raw suppliers

Sodium tetrachloroaluminate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 14-34
• Safety Statements: 22-26-27-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Na+].[Al-](Cl)(Cl)(Cl)Cl
• Uses: Sodium tetrachloroaluminate is used as Friedel-Crafts acylating agent , dehydrating and dehydrogenating agent in organic synthesis.

Technology Process of Sodium tetrachloroaluminate

There total 14 articles about Sodium tetrachloroaluminate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

aluminium trichloride (7446-70-0) + Na(1+)*NbCl6(1-)=NaNbCl6 (16920-10-8) → sodium tetrachloroaluminate (7784-16-9) + niobium pentachloride (10026-12-7)

Guidance literature:

In not given;

Reference yield:

sodium chloride (7647-14-5) → sodium tetrachloroaluminate (7784-16-9)

Guidance literature:

With aluminium trichloride;

Reference yield:

aluminium trichloride (7446-70-0) → sodium tetrachloroaluminate (7784-16-9)

Guidance literature:

With NaCl; In melt; AlCl3/NaCl melt (170-240°C), NaCl satd.;

DOI:10.1016/0013-4686(88)80205-6

upstream raw materials:

sodium chloride

aluminium trichloride

aluminium

tetrachlorosilane

Downstream raw materials:

aluminium

tetrafluoroaluminate^(1-)

AlClF₃^(1-)

AlCl₂F₂^(1-)

Refernces

• 1、 Macmillan, Malcolm G.,Cleaver, Brian. "Solubility of Nickel Chloride in Molten Sodium Tetrachloroaluminate saturated with Sodium Chloride over the Temperature Range 200-400 deg C". . p. 3817 - 3820. Retrieved 1993.
• 2、 Takami, Norio,Koura, Nobuyuki. "". . p. 1137 - 1142. Retrieved 1988.
• 3、 Krebs, Bernt,Greiwing, Horst,Brendel, Claus,Taulelle, Francis,Gaune-Escard, Marcelle,Berg, Rolf W.. "Crystallographic and 27Al NMR study on premelting phenomena in crystals of sodium tetrachloroaluminate". . p. 981 - 988. Retrieved 2008/10/08.