methyloxidanyl

Base Information

• Chemical Name: methyloxidanyl
• CAS No.: 2143-68-2
• Molecular Formula: CH3O
• Molecular Weight: 31.0342
• DSSTox Substance ID: DTXSID30944009
• Nikkaji Number: J273.897J,J2.183.040B
• Mol file: 2143-68-2.mol

Synonyms:Methoxy;Methoxy radical;Methoxyl;methyloxidanyl;Methyloxy;2143-68-2;CH3O;CHEBI:32772;DTXSID30944009;CH3-O(.)

Chemical Property of methyloxidanyl

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• XLogP3: -0.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 31.018389715
• Heavy Atom Count: 2
• Complexity: 2

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C[O]

Technology Process of methyloxidanyl

There total 57 articles about methyloxidanyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C7H7N2O → pyridine-3-carbonitrile (100-54-9,121697-66-3,1232169-17-3,68271-95-4) + methoxyl radical (2143-68-2)

Guidance literature:

With tris(p-anisyl)amine radical cation; In acetonitrile; Kinetics;

DOI:10.1021/ja030438+

Reference yield:

C7H7N2O → pyridine-4-carbonitrile (100-48-1) + methoxyl radical (2143-68-2)

Guidance literature:

In various solvent(s); Kinetics; ambient temperature;

DOI:10.1021/ja020768e

Reference yield:

C7H7N2O → pyridine-4-carbonitrile (100-48-1) + methoxyl radical (2143-68-2) + 4-cyano-N-methoxypyridinium (51342-22-4)

Guidance literature:

With 4-bromoanisole cation radical; In acetonitrile; at 23 ℃; Rate constant; Mechanism;

upstream raw materials:

methanol

methyl radical

deuteromethanol

methyl nitrite

Downstream raw materials:

formaldehyd

methane

Dimethyl ether

ethyl methyl ether

Refernces

• 1、 Migita, Catharina T.,Chaki,. Satoshi,Ogura, Kotaro. "ESR Spectroscopic Detection of Methoxyl Radicals Formed in the Photochemical Gas-Phase Reaction of Methane and Water". . p. 6368 - 6370. Retrieved 1989.
• 2、 Page, M.,Lin, M. C.,He, Yisheng,Choudhury, T. K.. "Kinetics of the Methoxy Radical Decomposition Reaction: Theory and Experiment". . p. 4404 - 4408. Retrieved 1989.
• 3、 Kwong, Bess C. L.,Tse, R. S.. "Chemiluminescence Studies of the Reaction between O(3P) Atoms and Methyl Ioide". . p. 823 - 827. Retrieved 1994.
• 4、 McCaulley, James A.,Moyle, Alfred M.,Golde, Michael F.,Anderson, Stuart M.,Kaufman, Frederick. "Kinetics of the Reactions of CH3O and CD3O with NO". . p. 4001 - 4009. Retrieved 1990.
• 5、 Enami, Shinichi,Yamanaka, Takashi,Kawasaki, Masahiro. "Near-infrared cavity ring-down spectroscopic study of the reaction of methylperoxy radical with nitrogen monoxide". body text. p. 80 - 81. Retrieved 2009/11/30.
• 6、 Williams, Skip,Knighton,Midey, Anthony J.,Viggiano,Irle, Stephan,Wang, Qingfang,Morokuma, Keiji. "Oxidation of alkyl ions, CnH2n+1+ (n = 1-5), in reactions with O2 and O3 in the gas phase". . p. 1980 - 1989. Retrieved 2007/10/03.