azanide; dichlororuthenium

Base Information

• Chemical Name: azanide; dichlororuthenium
• CAS No.: 63251-19-4
• Molecular Formula: Cl*Cl₂H₁₂N₄Ru
• Molecular Weight: 275.551
• Mol file: 63251-19-4.mol

Synonyms:

Chemical Property of azanide; dichlororuthenium

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of azanide; dichlororuthenium

There total 9 articles about azanide; dichlororuthenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

hydrogenchloride (7647-01-0,15364-23-5) + sodium tetrahydroborate (16940-66-2) + Ru(O2C6H3CO2)(NH3)4 (88288-72-6) → cis-tetramminedichlororuthenium(III) chloride (22327-28-2,29230-00-0,63251-19-4)

Guidance literature:

In hydrogenchloride; byproducts: 3,4-dihydroxybenzoic acid; Ru complex and acid mixing, NaBH4 carefull addn.; organic ligand extraction (ethylacetate), H2O2 addn. to aq. phase, heating, evapn. to dryness, residue recrystn. from aq. HCl;

DOI:10.1016/0020-1693(95)90086-L

Reference yield: 65.0%

pentaamminechlororuthenium(III) dichloride + calcium dithionate + oxalic acid (144-62-7,97993-78-7) → cis-tetramminedichlororuthenium(III) chloride (22327-28-2,29230-00-0,63251-19-4)

Guidance literature:

With ammonium hydroxide; Ar; a mixture of the starting complex and NH4OH was refluxed for 25 min; addn. of Ca(SO3)2; isoln. of (OH)(NH3)5Ru(SO3)2at 0° C; dissoln. in oxalic acid; reflux for 5 min; isolation of the oxalato-intermediate; reflux of a HCl-soln. for 10 min;; hot filtration; addn. of ethanol to the filtrate; cooling overnight at 0 ° C; filtration; recrystn. from warm 8 M HCl/ethanol; chilling at 0 ° C for 8 h;;

Reference yield: 35.0%

hydrazine dihydrochloride (14011-37-1,5341-61-7) + dichlorotetrakis(dimethyl sulfoxide)ruthenium(II) (89395-66-4,75766-08-4,41290-68-0,90698-13-8,482618-33-7,194497-67-1,64376-67-6,59091-96-2,72904-47-3,61779-29-1) → cis-(dichloro)tetrammineruthenium(III) chloride (29230-00-0,22327-28-2,63251-19-4)

Guidance literature:

In water; heating cis-(RuCl2(Me2SO)4) and N2H4*2HCl in water at 90-95°C for 5 h; elem. anal.;

upstream raw materials:

hydrogenchloride

cis-tetraammineaquachlororuthenium(III)

oxalic acid

sodium tetrahydroborate

Downstream raw materials:

trans-tetramminedichlororuthenium(III) dichloriodide

mer-triaamminetrichlororuthenium(III)

cis-[tetraammineruthenium(III)(tetrachlorocatecholate)]PF₆*H₂O

Refernces

• 1、 Boggs, Susan E.,Clarke, Richard E.,Ford, Peter C.. "Syntheses of cis- and trans-tetraamminedichlororuthenium(III) chloride". . p. 129 - 130. Retrieved 2008/10/08.
• 2、 Salaymeh, Faleh,Berhane, Samson,Yusof, Rohana,De La Rosa, Roger,Fung, Ella Y.,Matamoros, Regina,Lau, Kent W.,Zheng, Qian,Kober, Edward M.,Curtis, Jeff C.. "Electronic coupling in mixed-valence binuclear ruthenium ammine complexes as probed by an electrochemical method and an extension of Mulliken's theory of donor-acceptor interactions". . p. 3895 - 3908. Retrieved 2008/10/08.