Bismuthine, triethyl-

Base Information

• Chemical Name: Bismuthine, triethyl-
• CAS No.: 617-77-6
• Molecular Formula: C6H15 Bi
• Molecular Weight: 296.166
• European Community (EC) Number: 210-528-5
• UNII: 6L8XG4MR2V
• DSSTox Substance ID: DTXSID7060675
• Mol file: 617-77-6.mol

Synonyms:Bismuthine, triethyl-;Triethylbismuth;triethylbismuthane;Triethylbismuthine;617-77-6;6L8XG4MR2V;EINECS 210-528-5;Triethylbismuthine #;C6H15Bi;UNII-6L8XG4MR2V;C6-H15-Bi;DTXSID7060675

Chemical Property of Bismuthine, triethyl-

Chemical Property:

• Melting Point: -127.35°C
• Boiling Point: 104-105 °C(Press: 76 Torr)
• PSA: 0.00000
• Density: 1.8200
• LogP: 2.85870
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 296.09777
• Heavy Atom Count: 7
• Complexity: 25.7

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[Bi](CC)CC

Technology Process of Bismuthine, triethyl-

There total 24 articles about Bismuthine, triethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

bismuth (7440-69-9) + Na(1+)*{Al(C2H5)3OC2H5}(1-)=Na{Al(C2H5)3OC2H5} → triethylbismuth (617-77-6)

Guidance literature:

In water; Electrolysis; with Bi anode, from aq. soln. of Na{Al(C2H5)3(OC2H5)}, under CO2, H2, N2, Ar;

Reference yield: 94.0%

tetraethyldibismuthane (81956-27-6) + diethyl ditelluride (26105-63-5) → Et2BiTeEt + triethylbismuth (617-77-6)

Guidance literature:

Inert atmosphere;

DOI:10.1002/ejic.201402471

Reference yield: 89.0%

triethylaluminum (97-93-8) + bismuth(III) chloride (7787-60-2) + 1-Methylnaphthalene (90-12-0,34475-76-8) → triethylbismuth (617-77-6)

Guidance literature:

With NaCl; under CO2, H2, N2, Ar; distn.;

upstream raw materials:

ethylmagnesium bromide

diethylzinc

triethylaluminum

ethyl iodide

Downstream raw materials:

ethylmercury(II) chloride

ethylmercury ⁽¹⁺⁾; bromide

ethane

diethyl ether

Refernces

• 1、 Gilman,Nelson. "-". . p. 935. Retrieved 1937.
• 2、 Gilman, H.,Apperson, L. D.. "". . p. 162 - 168. Retrieved 1939.
• 3、 Winchester. "". . p. 1747. Retrieved 1971.
• 4、 Petiot, Pauline,Gagnon, Alexandre. "Palladium-catalyzed cross-coupling reaction of trialkylbismuthines with 2-haloazines and diazines". . p. 1615 - 1624. Retrieved 2016/10/12.