silver(I) o-nitrobenzoate

Base Information

• Chemical Name: silver(I) o-nitrobenzoate
• CAS No.: 72247-99-5
• Molecular Formula: C7H5NO4
• Molecular Weight: 273.981
• Mol file: 72247-99-5.mol

Synonyms:

Chemical Property of silver(I) o-nitrobenzoate

Chemical Property:

• Boiling Point: 340.7°Cat760mmHg
• Flash Point: 157.5°C
• Density: 1.468g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of silver(I) o-nitrobenzoate

There total 2 articles about silver(I) o-nitrobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

ortho-nitrobenzoic acid (552-16-9,104810-18-6) + silver(l) oxide (20667-12-3) → silver(I) o-nitrobenzoate (72247-99-5)

Guidance literature:

In acetonitrile; at 20 ℃; for 2h; Darkness;

DOI:10.1021/jacs.7b13305

Reference yield:

ortho-nitrobenzoic acid (552-16-9,104810-18-6) + silver nitrate → silver(I) o-nitrobenzoate (72247-99-5)

Guidance literature:

In water; NaOH added successively to a soln. of Ag-salt and o-nitrobenzoic acid until pH 5; precipitate redissolved in hot water, slowly evapd. in the dark at roomtemp.;

DOI:10.1107/S0108270194001381

Reference yield:

silver(I) o-nitrobenzoate (72247-99-5) → 1-nitro-2-(2-nitrophenyl)benzene (2436-96-6) + nitrobenzene (98-95-3,26969-40-4)

Guidance literature:

Multi-step reaction with 2 steps

1: acetonitrile / Darkness

2: d₇-N,N-dimethylformamide / 24 h / 100 °C / Inert atmosphere; Glovebox; Sealed tube; Darkness

In d₇-N,N-dimethylformamide; acetonitrile;

DOI:10.1021/jacs.7b13305

upstream raw materials:

ortho-nitrobenzoic acid

silver(l) oxide

Downstream raw materials:

2-nitrophenyl bromide

1,2-bis-(2-nitro-benzoyloxy)-ethane

nitrobenzene

1-nitro-2-(2-nitrophenyl)benzene

Refernces

• 1、 Daley, Ryan A.,Morrenzin, Aaron S.,Neufeldt, Sharon R.,Topczewski, Joseph J.. "Gold Catalyzed Decarboxylative Cross-Coupling of Iodoarenes". supporting information. p. 13210 - 13218. Retrieved 2020/09/01.