Nickel, tetrakis(triphenyl phosphite-kappaP)-, (T-4)-

Base Information

• Chemical Name: Nickel, tetrakis(triphenyl phosphite-kappaP)-, (T-4)-
• CAS No.: 14221-00-2
• Molecular Formula: C72H60 Ni O12 P4
• Molecular Weight: 1299.85
• Hs Code.: 29209090
• European Community (EC) Number: 622-848-6
• Mol file: 14221-00-2.mol

Synonyms:14221-00-2;nickel;triphenyl phosphite;Tetrakis(triphenylphosphite)nickel(0);tetrakis(triphenyl phosphite)nickel(0);Nickel, tetrakis(triphenyl phosphite-kappaP)-, (T-4)-;Nickel, tetrakis(triphenyl phosphite-.kappa.P)-, (T-4)-;Nickel tetrakis(triphenoxyphosphine);C72H60NiO12P4;Nickel tetrakis(triphenyl phosphite);C72-H60-Ni-O12-P4;Nickel, tetrakis(triphenyl phosphite-P)-, (T-4)-

Chemical Property of Nickel, tetrakis(triphenyl phosphite-kappaP)-, (T-4)-

Chemical Property:

• Melting Point: 145 °C (dec.)(lit.)
• PSA: 165.12000
• LogP: 21.80120
• Storage Temp.: Refrigerator (+4°C)
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 12
• Rotatable Bond Count: 24
• Exact Mass: 1298.238867
• Heavy Atom Count: 89
• Complexity: 247

Purity/Quality:

98%Min ^*data from raw suppliers

Tetrakis(triphenylphosphite)nickel(0) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 36/37/38-40-43
• Safety Statements: 26-36/37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)OP(OC2=CC=CC=C2)OC3=CC=CC=C3.C1=CC=C(C=C1)OP(OC2=CC=CC=C2)OC3=CC=CC=C3.C1=CC=C(C=C1)OP(OC2=CC=CC=C2)OC3=CC=CC=C3.C1=CC=C(C=C1)OP(OC2=CC=CC=C2)OC3=CC=CC=C3.[Ni]
• Uses: Catalyst for alkene and alkyne hydrocyanation and styrenedimerization

Technology Process of Nickel, tetrakis(triphenyl phosphite-kappaP)-, (T-4)-

There total 19 articles about Nickel, tetrakis(triphenyl phosphite-kappaP)-, (T-4)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

triphenyl phosphite (101-02-0) + hexaaquanickel(II) nitrate → tetrakis(triphenylphosphite)nickel(0) (14221-00-2)

Guidance literature:

With 2-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)-5,5-dimethyl-1,3,2-dioxaborinane; In methanol; at 23 ℃; for 18h;

DOI:10.1021/acs.organomet.1c00325

Reference yield: 74.0%

triphenyl phosphite (101-02-0) + trans-[NiIICl2(H2O)4]·2H2O → tetrakis(triphenylphosphite)nickel(0) (14221-00-2)

Guidance literature:

With 2-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)-5,5-dimethyl-1,3,2-dioxaborinane; In methanol; at 23 ℃; for 18h; Inert atmosphere;

DOI:10.1021/acs.organomet.1c00325

Reference yield: 68.0%

triphenyl phosphite (101-02-0) + nickel(II) bromide trihydrate → tetrakis(triphenylphosphite)nickel(0) (14221-00-2)

Guidance literature:

With 2-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)-5,5-dimethyl-1,3,2-dioxaborinane; In methanol; at 23 ℃; for 18h;

DOI:10.1021/acs.organomet.1c00325

upstream raw materials:

triphenyl phosphite

tetracarbonyl nickel

nickel

nickel(II) acetylacetonate

Downstream raw materials:

[P(OC₆H₅)3]2NiI(CN)

[P(OC₆H₅)3]2Ni(SCN)2

[P(OC₆H₅)3]2NiBr(CN)

[P(OC₆H₅)3]2Ni(SeCN)2

Refernces

• 1、 Chow, Yuan L.,Buono-Core, Gonzalo E.,Lee, Carolyn W. B.,Scaiano, J. C.. "Sensitied Photoreduction of Bis(acetylacetonato)nicket(II) by Triplet State Aromatic Ketones". . p. 7620 - 7627. Retrieved 1986.
• 2、 Frem,Massabni,Massabni,Mauro. "Syntheses and luminescent properties of tetrahedral nickel(0) complexes". . p. 53 - 58. Retrieved 2008/10/08.