Propyl 2,4-dichlorophenoxyacetate

Base Information

• Chemical Name: Propyl 2,4-dichlorophenoxyacetate
• CAS No.: 1928-61-6
• Molecular Formula: C11H12 Cl2 O3
• Molecular Weight: 263.12
• Hs Code.: 2918990090
• European Community (EC) Number: 217-677-5
• UNII: M054QZ572Y
• DSSTox Substance ID: DTXSID4062066
• Nikkaji Number: J80.347B
• Wikidata: Q27283288
• Mol file: 1928-61-6.mol

Synonyms:Propyl 2,4-dichlorophenoxyacetate;2,4-D-propyl;2,4-D propyl ester;1928-61-6;propyl 2-(2,4-dichlorophenoxy)acetate;2,4-D-propyl [ISO];UNII-M054QZ572Y;2,4-D, PROPYL ESTER;M054QZ572Y;Acetic acid, (2,4-dichlorophenoxy)-, propyl ester;EINECS 217-677-5;DTXSID4062066;propyl 2,4-dichloro-phenoxyacetate;AKOS017265306;2,4-dichloro-phenoxyacetic acid propyl ester;(2,4-Dichlorophenoxy)acetic acid propyl ester;Q27283288;ACETIC ACID, 2-(2,4-DICHLOROPHENOXY)-, PROPYL ESTER

Chemical Property of Propyl 2,4-dichlorophenoxyacetate

Chemical Property:

• Vapor Pressure: 0.000184mmHg at 25°C
• Boiling Point: 328.9°Cat760mmHg
• Flash Point: 129.6°C
• PSA: 35.53000
• Density: 1.272g/cm³
• LogP: 3.32540
• XLogP3: 4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 6
• Exact Mass: 262.0163496
• Heavy Atom Count: 16
• Complexity: 223

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCOC(=O)COC1=C(C=C(C=C1)Cl)Cl

Technology Process of Propyl 2,4-dichlorophenoxyacetate

There total 4 articles about Propyl 2,4-dichlorophenoxyacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

propan-1-ol (71-23-8) + 2,4-Dichlorophenoxyacetic acid (94-75-7,89300-30-1) → propyl 2,4-dichlorophenoxyacetate (1928-61-6)

Guidance literature:

dimethyltin dichloride; for 2h; Heating;

DOI:10.1016/S0040-4039(00)96364-0

Reference yield:

triethylsilane (617-86-7) + (2,4-dichloro-phenoxy)-acetic acid allyl ester (58965-05-2) → propane (74-98-6) + hexaethyldisilane (1633-09-6) + propyl 2,4-dichlorophenoxyacetate (1928-61-6) + 2,4-dichloro-1-triethylsiloxybenzene (130084-96-7) + C14H20Cl2O3Si (130084-92-3) + (2,4-Dichloro-phenoxy)-acetic acid 3-triethylsilanyl-propyl ester

Guidance literature:

dihydrogen hexachloroplatinate; In isopropyl alcohol; at 100 ℃; for 7h; Product distribution; various esters, other catalyst, other temp. and time;

Reference yield:

n-propyl chloracetate (5396-24-7) + 2,4-dichlorophenol (120-83-2,40477-79-0) → propyl 2,4-dichlorophenoxyacetate (1928-61-6)

Guidance literature:

2,4-dichlorophenol; With potassium hydroxide; In water; at 90 ℃;

n-propyl chloracetate; In water; at 100 ℃; for 0.5h;

upstream raw materials:

propan-1-ol

2,4-Dichlorophenoxyacetic acid

triethylsilane

(2,4-dichloro-phenoxy)-acetic acid allyl ester

Downstream raw materials:

2,4-Dichlorophenoxyacetic acid

Refernces

• 1、 -. "A method for preparing 2, 4 - dichlorophenoxyacetic acid (by machine translation)". Paragraph 0038; 0039. . Retrieved 2018/09/08.
• 2、 Kumar, Amal K.,Chattopadhyay, Tapas K.. "CATALYTIC ROLE OF DIORGANOTIN DICHLORIDE IN ESTERIFICATION OF CARBOXYLIC ACIDS". . p. 3713 - 3714. Retrieved 2007/10/02.