Diphenyllead dichloride

Base Information

• Chemical Name: Diphenyllead dichloride
• CAS No.: 2117-69-3
• Molecular Formula: C12H10 Cl2 Pb
• Molecular Weight: 432.317
• Hs Code.: 2931900090
• European Community (EC) Number: 218-325-3
• NSC Number: 173034
• DSSTox Substance ID: DTXSID10175410
• Wikidata: Q21146314
• Mol file: 2117-69-3.mol

Synonyms:Diphenyllead dichloride;2117-69-3;dichloro(diphenyl)plumbane;Dichlorodiphenyllead;Plumbane, dichlorodiphenyl-;Dichlorodiphenylplumbane;Diphenyldichloroplumbane;Lead, dichlorodiphenyl-;EINECS 218-325-3;NSC 173034;AI3-50635;DIPHENYL LEAD DICHLORIDE;Dichlorophenylplumbane;diphenyle lead dichloride;DIPHENYLLEADDICHLORIDE;SCHEMBL3141193;DTXSID10175410;NSC173034;AKOS024431844;NSC-173034;LS-117854;FT-0766244;Q21146314

Chemical Property of Diphenyllead dichloride

Chemical Property:

• Vapor Pressure: 4.07E-05mmHg at 25°C
• Melting Point: 249-251°C (dec.)
• Boiling Point: 362.3°Cat760mmHg
• Flash Point: 172.9°C
• PSA: 0.00000
• Density: g/cm³
• LogP: 3.97180
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 431.99261
• Heavy Atom Count: 15
• Complexity: 174

Purity/Quality:

99% ^*data from raw suppliers

DICHLORODIPHENYLLEAD Aldrich ^*data from reagent suppliers

Safty Information:

• Statements: 20/22-33-50/53-61
• Safety Statements: 45-53

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Pb](C2=CC=CC=C2)(Cl)Cl

Technology Process of Diphenyllead dichloride

There total 6 articles about Diphenyllead dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

triphenyl lead iron tetracarbonyl → Hg*Fe*4CO = HgFe(CO)4 + triphenyllead(IV) chloride (1153-06-6) + diphenyllead(IV) dichloride (2117-69-3) + phenylmercury(II) chloride (100-56-1)

Guidance literature:

With mercury dichloride; In diethyl ether;

Reference yield:

tris(pentafluorophenyl)antimony dichloride (100296-18-2,55678-65-4) + hexaphenyl diplumbane (3124-01-4) → Tetraphenyllead (595-89-1) + diphenyllead(IV) dichloride (2117-69-3) + tris(pentafluorophenyl)antimony (3910-39-2)

Guidance literature:

In chloroform; to refluxing soln. of Ph2Pb2 in chloroform is added dropwise chloroformsoln. of (C6F5)3SbCl2 and mixt. is refluxed for 5 h; mixt. is cooled at ice temp., solid is filtered off;

DOI:10.1016/S0277-5387(00)84497-6

Reference yield:

diphenyldicyclopentadienylplumbane (82737-35-7) → diphenyllead(IV) dichloride (2117-69-3)

Guidance literature:

With HCl; In benzene; HCl gas, at room temp, under Ar in the dark; elem. anal.;

DOI:10.1039/DT9820001055

upstream raw materials:

hydrogenchloride

Tetraphenyllead

diphenyldicyclopentadienylplumbane

tris(pentafluorophenyl)antimony dichloride

Downstream raw materials:

diphenyllead(IV) diacetate

(C₆H₅)2Pb(Co(CO)4)2

Refernces

• 1、 Herzog, Uwe,Rheinwald, Gerd. "Silicon-lead chalcogenides of the types Me4Si2(E)2PbPh2 and Ph2Pb(E)2Si2Me2 (E)2PbPh2 (E = S, Se) and related compounds containing tin and antimony". . p. 220 - 225. Retrieved 2007/10/03.
• 2、 Gaffney, Christine,Harrison, Philip G.. "The Chemistry of (Cyclopentadienyl)phenyl-lead(IV) Compounds". . p. 1055 - 1060. Retrieved 2007/10/02.