phenylsulfanyl

Base Information

• Chemical Name: phenylsulfanyl
• CAS No.: 4985-62-0
• Molecular Formula: C6H5S
• Molecular Weight: 111.188
• Mol file: 4985-62-0.mol

Synonyms:

Chemical Property of phenylsulfanyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of phenylsulfanyl

There total 21 articles about phenylsulfanyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tert.-butylhydroperoxide (75-91-2) + thiophenol (108-98-5) → phenylthiyl (4985-62-0) + tert-butyl alcohol (75-65-0)

Guidance literature:

In tetrachloromethane; at 130 ℃; for 3h; competition reaction with other thiols in various solvents; relative reactivities;

DOI:10.1021/jo00053a035

Reference yield:

C10H13S2 → thiophene (110-01-0) + phenylthiyl (4985-62-0)

Guidance literature:

In benzene; at 50 ℃; Rate constant;

Reference yield:

mercapto radical (7704-34-9) + thiophenol (108-98-5) → phenylthiyl (4985-62-0) + hydrogen sulfide (7783-06-4)

Guidance literature:

other Radiation; with (60)Co ray; at room temp.;

DOI:10.1021/j100863a013

upstream raw materials:

benzophenone

tert.-butylhydroperoxide

thiophenol

diphenyldisulfane

Downstream raw materials:

2-phenylisopropyl radical

thiophenol

4-methoxy-benzyl

Refernces

• 1、 El-Agamey, Ali,McGarvey, David J.. "First direct observation of reversible oxygen addition to a carotenoid-derived carbon-centered neutral radical". . p. 3957 - 3960. Retrieved 2005.
• 2、 Scott, T. W.,Liu, S. N.. "Picosecond Geminate Recombination of Phenylthiyl Free-Radical Pairs". . p. 1393 - 1396. Retrieved 1989.
• 3、 Kimura, Yoshifumi,Sugihara, Kohei,Terazima, Masahide,Hirota, Noboru. "Study on the Photolysis Quantum Yield of Diphenyl Disulfide by the Transient Grating Method". . p. 2657 - 2664. Retrieved 1997.
• 4、 Tanaka, Miyuki,Yago, Tomoaki,Wakasa, Masanobu. "Primary photochemical process of thiobenzophenone as studied by laser flash photolysis". body text. p. 1086 - 1087. Retrieved 2010/06/20.