BAS 00110142

Base Information

• Chemical Name: BAS 00110142
• CAS No.: 52118-10-2
• Molecular Formula: C16H14O4
• Molecular Weight: 270.285
• Hs Code.: 2912299000
• Mol file: 52118-10-2.mol

Synonyms:benzaldehyde,2,2'-[1,2-ethanediylbis(oxy)]bis;HMS2501H14;

Chemical Property of BAS 00110142

Chemical Property:

• Boiling Point: 470°Cat760mmHg
• Flash Point: 210.6°C
• PSA: 52.60000
• Density: 1.219g/cm³
• LogP: 2.76940

Purity/Quality:

99% ^*data from raw suppliers

2,2'-[Ethane-1,2-diylbis(oxy)]dibenzaldehyde ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of BAS 00110142

There total 16 articles about BAS 00110142 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

salicylaldehyde (90-02-8) + ethylene dibromide (106-93-4) → 2,2'-[1,2-ethanediylbis(oxy)]bisbenzaldehyde (52118-10-2)

Guidance literature:

With potassium carbonate; potassium iodide; In acetonitrile; for 12h; Reflux;

DOI:10.1055/s-0029-1216631

Reference yield: 80.0%

2-methyl-benzyl alcohol (89-95-2) + ethylene dibromide (106-93-4) → 2,2'-[1,2-ethanediylbis(oxy)]bisbenzaldehyde (52118-10-2)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 80 ℃;

DOI:10.1055/s-2003-41004

Reference yield: 76.0%

1,2-bis-tosyloxyethane (6315-52-2) + sodium salicylate (3116-83-4) → 2,2'-[1,2-ethanediylbis(oxy)]bisbenzaldehyde (52118-10-2)

Guidance literature:

upstream raw materials:

salicylaldehyde

ethylene dibromide

1,2-bis-tosyloxyethane

sodium salicylate

Downstream raw materials:

C₂₄H₂₄N₆O₈

1-(4-fluoro-phenyl)-3-[2-(2-{2-[3-(4-fluoro-phenyl)-3-oxo-propenyl]-phenoxy}-ethoxy)-phenyl]-propenone

1-(4-chloro-phenyl)-3-[2-(2-{2-[3-(4-chloro-phenyl)-3-oxo-propenyl]-phenoxy}-ethoxy)-phenyl]-propenone

Refernces

• 1、 Moorthy, Madhappan Santha,Park, Sung Soo,Selvaraj,Ha, Chang-Sik. "Cyclic ligand functionalized mesoporous silica (SBA-15) for selective adsorption of Co2+ion from artificial seawater". . p. 8891 - 8897. Retrieved 2014.
• 2、 Kathiravan, Subban,Raghunathan, Raghavachary. "A facile one-pot three-component synthesis of macrocyclic imidazolidines by [3+2] cycloaddition reaction of azomethine ylides". . p. 1126 - 1130. Retrieved 2009.
• 3、 Gao, Su-Xia,Xu, Xin,Zhang, Yang,Dong, Wen-Kui. "A Bis(Salamo)-Based Fluorogenic Sensor for Highly Selective and Sequential Recognition of Cu2+ and B4O72? Ions in Semi-Aqueous Medium". . p. 817 - 833. Retrieved 2021.
• 4、 Maharramov,Ramazanov,Guliyeva,Huseynzada,Hasanova,Shikhaliyev,Eyvazova,Hajiyeva,Mamedov,Aghayev. "Synthesis, investigation of the new derivatives of dihydropyrimidines and determination of their biological activity". . p. 39 - 43. Retrieved 2017.
• 5、 Arockia Samy,Alexander. "A new dinucleating bridging ligand 1,2-bis(2-(1H-imidazo[4,5-f]-[1,10] phenanthrolin-2-yl)phenoxy)ethane and its dinuclear ruthenium(II) complexes: Syntheses, characterization, luminescence, and electrochemical properties". . p. 247 - 254. Retrieved 2012.
• 6、 Bian, Ruo-Nan,Dong, Wen-Kui,Li, Ya-Juan,Wang, Ji-Fa,Zhang, Yang. "Fluorescent chemical sensor based on double N2O2 cavities for continuous recognition of Cu2+ and Al3+". . . Retrieved 2020.
• 7、 Kaur, Sarbjeet,Shiekh, Bilal Ahmad,Kaur, Damanjit,Kaur, Inderpreet. "Highly sensitive sensing of Fe(III) harnessing Schiff based ionophore: An electrochemical approach supported with spectroscopic and DFT studies". . . Retrieved 2021.
• 8、 Zhao, Li,Zhang, Yu-Jie,Zhang, Shou-Ting,Guo, Hong-Xia,Cheng, Qian. "Synthesis and crystal structure of 2,2'-(1,2-Ethylenedioxy)bisbenzaldehyde O,O'-diethyldioxime". . p. 5076 - 5078. Retrieved 2013.
• 9、 Bahrampour, Marzyeh,Fausto, Rui,Golbedaghi, Reza,Justino, Licínia L. G.. "A novel fluorescent chemosensor for Cu2+ ion based on a new hexadentate ligand receptor: X-ray single crystal of the perchlorate salt of the ligand, ion selectivity assays and TD-DFT study". . . Retrieved 2021.
• 10、 Banaei, A. R.,Pourali, A. R.,Rezazadeh, B.,Tabari, S.. "Co(II) Schiff base Complexes Encapsulated in the Nanopores of Zeolite Y as Heterogeneous Catalysts for Selective Epoxidation of Alkenes with Molecular Oxygen". . p. 424 - 437. Retrieved 2021/07/16.