PENTAERYTHRITOL TRICHLOROHYDRIN

Base Information

• Chemical Name: PENTAERYTHRITOL TRICHLOROHYDRIN
• CAS No.: 813-99-0
• Molecular Formula: C5H9 Cl3 O
• Molecular Weight: 191.485
• Hs Code.: 2905590090
• Mol file: 813-99-0.mol

Synonyms:2,2-Bis(chloromethyl)-3-chloro-1-propanol;2,2-Bis(chloromethyl)-3-chloropropanol; 3-Chloro-2,2-bis(chloromethyl)-1-propanol;NSC 405661; NSC 524090; Pentaerythritol trichloride; Pentaerythritoltrichlorohydrin; Pentaerythrityl trichlorohydrin

Chemical Property of PENTAERYTHRITOL TRICHLOROHYDRIN

Chemical Property:

• Vapor Pressure: 3.38E-05mmHg at 25°C
• Refractive Index: 1.5300 (estimate)
• Boiling Point: 316.8 °C at 760 mmHg
• Flash Point: 145.4 °C
• PSA: 20.23000
• Density: 1.341 g/cm³
• LogP: 1.68150
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C

Purity/Quality:

98%,99%, ^*data from raw suppliers

3-Chloro-2,2-bis(chloromethyl)propan-1-ol ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of PENTAERYTHRITOL TRICHLOROHYDRIN

There total 9 articles about PENTAERYTHRITOL TRICHLOROHYDRIN which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

Pentaerythritol (115-77-5) → 3-chloro-(2,2-chloromethyl)propan-1-ol (813-99-0)

Guidance literature:

With pyridine; thionyl chloride; at 65 - 130 ℃; for 22h;

Reference yield:

Pentaerythritol (115-77-5) → pentaerythrityl tetrachloride (3228-99-7) + 3-chloro-(2,2-chloromethyl)propan-1-ol (813-99-0)

Guidance literature:

With pyridine; thionyl chloride; at 120 - 130 ℃; Yield given. Yields of byproduct given;

DOI:10.1021/jo00119a057

Reference yield:

Pentaerythritol (115-77-5) → 2,2-bis(chloromethyl)-1,3-propanediol (2209-86-1) + pentaerythrityl tetrachloride (3228-99-7) + 3-chloro-(2,2-chloromethyl)propan-1-ol (813-99-0)

Guidance literature:

With pyridine; thionyl chloride; for 14h; Yield given. Yields of byproduct given; Heating;

DOI:10.1016/S0022-1139(00)80471-6

upstream raw materials:

Pentaerythritol

acetic acid-(3-chloro-2,2-bis-chloromethyl-propyl ester)

3-chloro-2,2-bis-chloromethyl-propionic acid methyl ester

3,3-bis(chloromethyl)oxetane

Downstream raw materials:

3,3-bis-phenoxymethyl-oxetane

α,α,α-tris(hydroxymethyl)acetic acid

1-(3,5-Bis-trifluoromethyl-phenyl)-3-chloromethyl-azetidine-3-carboxylic acid ethyl ester

N-(3,5-Bis-trifluoromethyl-phenyl)-3-chloro-2,2-bis-chloromethyl-propionamide

Refernces

• 1、 Mondanaro, Kathleen R.,Dailey, William P.,Pal, Rajib,Dong, Yan,Belica, Peter,Wolff, Steven. "3-Chloro-2-(chloromethyl)-1-propene [1-Propene, 3-chloro-2-(chloromethyl)-]". . p. 89 - 89. Retrieved 2017/09/20.
• 2、 Ameduri, Bruno,Boutevin, Bernard,Karam, Lina. "Synthesis and properties of poly". . p. 43 - 48. Retrieved 2007/10/02.