PHENANTHRENE-D10

Base Information

• Chemical Name: PHENANTHRENE-D10
• CAS No.: 1517-22-2
• Molecular Formula: C14D10
• Molecular Weight: 188.154
• Hs Code.: 28459000
• Mol file: 1517-22-2.mol

Synonyms:Perdeuterated phenanthrene;Perdeuteriophenanthrene;Perdeuterophenanthrene;[2H10]Phenanthracene;Phenanthrene-d10(6CI,7CI,8CI,9CI);

Chemical Property of PHENANTHRENE-D10

Chemical Property:

• Vapor Pressure: 0.000206mmHg at 25°C
• Melting Point: 98-100 °C(lit.)
• Refractive Index: 1.714
• Boiling Point: 337.4 °C at 760 mmHg
• Flash Point: 146.6 °C
• PSA: 0.00000
• Density: 1.194 g/cm³
• LogP: 3.99300
• Storage Temp.: 2-8°C

Purity/Quality:

98%,99%, ^*data from raw suppliers

Phenanthrene-d10 ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn,N,T
• Hazard Codes: Xn,N,T,F
• Statements: 22-36/37/38-50/53-63-43-23/24/25-45-39/23/24/25-52/53-11-40
• Safety Statements: 26-60-61-36/37-24/25-23-53-45-16

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: Phenanthrene is a polycyclic aromatic hydrocarbons, an environmental pollutant. May be used as an analytical standard

Technology Process of PHENANTHRENE-D10

There total 2 articles about PHENANTHRENE-D10 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

phenanthrene (85-01-8) → decadeuterio-phenanthrene (1517-22-2)

Guidance literature:

With water-d2; hydrogen chloride; at 250 ℃; for 50h;

Reference yield:

→ decadeuterio-phenanthrene (1517-22-2)

Guidance literature:

Reference yield:

decadeuterio-phenanthrene (1517-22-2) → 1,3-diphenyl<4,5,6,7,8,9,10,11-2H8>cyclopentaphenanthren-2-one (113474-60-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 84 percent / CrO₃, aq. AcOH / 0.5 h / 60 °C

2: 50 percent / KOH / ethanol / 0.08 h / Heating

With chromium(VI) oxide; potassium hydroxide; acetic acid; In ethanol;

DOI:10.1021/jo00243a016

upstream raw materials:

phenanthrene

Downstream raw materials:

1-hydroxyphenanthrene-d₉

1,3-diphenyl<4,5,6,7,8,9,10,11-2H8>cyclopentaphenanthren-2-one

Refernces

• 1、 Junk, Thomas,Catallo, W. James. "Preparative supercritical deuterium exchange in arenes and heteroarenes". . p. 3445 - 3448. Retrieved 2007/10/03.