tert-Butyldichlorophosphine

Base Information Edit

Chemical Name:tert-Butyldichlorophosphine
CAS No.:25979-07-1
Molecular Formula:C4H9Cl2P
Molecular Weight:158.995
Hs Code.:29310099
European Community (EC) Number:247-386-9
UNII:Z4H8CP6FBP
DSSTox Substance ID:DTXSID00180639
Nikkaji Number:J308.364K
Wikidata:Q72502902
Mol file:25979-07-1.mol

Synonyms:tert-Butyldichlorophosphine;25979-07-1;t-Butyldichlorophosphine;tert-butyl(dichloro)phosphane;tert-C4H9PCl2;Z4H8CP6FBP;Phosphonous dichloride, (1,1-dimethylethyl)-;Phosphonous dichloride, P-(1,1-dimethylethyl)-;EINECS 247-386-9;C4H9Cl2P;tert-Butylphosphine dichloride;tert-Butylphosphonous dichloride;MFCD00013615;UNII-Z4H8CP6FBP;dichloro-tert-butylphosphine;tert-butyl(dichloro)phosphine;C4-H9-Cl2-P;SCHEMBL1456657;DTXSID00180639;tert-Butyldichlorophosphine, 98%;tert-butyl-bis(chloranyl)phosphane;tert-Butylphosphonous dichloride #;AKOS015910206;FT-0638562;D94628;A818123;J-016202

Suppliers and Price of tert-Butyldichlorophosphine

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Strem Chemicals
t-Butyldichlorophosphine, 98%
2g
$ 27.00

Strem Chemicals
t-Butyldichlorophosphine, 98%
10g
$ 82.00

Sigma-Aldrich
tert-Butyldichlorophosphine 98%
10g
$ 98.10

Sigma-Aldrich
tert-Butyldichlorophosphine solution 1.0M in diethyl ether
100ml
$ 94.90

JR MediChem
Phosphonousdichloride,P-(1,1-dimethylethyl)- 96%
100g
$ 918.00

Chemenu
tert-butyl(dichloro)phosphane 95%+
100g
$ 1012.00

Chemenu
tert-butyl(dichloro)phosphane 95%+
50g
$ 524.00

Chemenu
tert-butyl(dichloro)phosphane 95%+
1000g
$ 4640.00

American Custom Chemicals Corporation
TERT-BUTYLDICHLOROPHOSPHINE 95.00%
10G
$ 1190.92

American Custom Chemicals Corporation
TERT-BUTYLDICHLOROPHOSPHINE 95.00%
1G
$ 160.44

Total 55 raw suppliers

Chemical Property of tert-Butyldichlorophosphine Edit

Chemical Property:

Appearance/Colour:white to light yellow crystal powder
Vapor Pressure:5.57mmHg at 25°C
Melting Point:44-49 °C(lit.)
Boiling Point:147.564 °C at 760 mmHg
Flash Point:43.045 °C
PSA：13.59000
Density:0.766 g/mL at 25 °C
LogP:3.57440
Storage Temp.:Flammables area
Sensitive.:Air Sensitive
Water Solubility.:Reacts with water. Soluble in n-Pentane, n-Hexane, Ether, Toluene,THF. tert-Butyldichlorophosphine is infinitely soluble in hydr
XLogP3:2.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:0
Exact Mass:157.9818927
Heavy Atom Count:7
Complexity:55.2

Purity/Quality:

98% ^*data from raw suppliers

t-Butyldichlorophosphine, 98% ^*data from reagent suppliers

Safty Information:

Pictogram(s): C,T,F
Hazard Codes:C,T,F
Statements: 14-34-29-23/24/25-17-11-67-22-19
Safety Statements: 26-27-28-36/37/39-45-8-16

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)P(Cl)Cl
Uses Reactant for the synthesis of alkali metal complexes. As intermediates. tert-Butyldichlorophosphine (TBDCP) is used primarily in the preparation of monoand bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions.

Technology Process of tert-Butyldichlorophosphine

There total 20 articles about tert-Butyldichlorophosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%