Peroxypropionic acid

Base Information

• Chemical Name: Peroxypropionic acid
• CAS No.: 4212-43-5
• Molecular Formula: C3H6O3
• Molecular Weight: 90.0788
• Hs Code.: 2918300090
• European Community (EC) Number: 224-139-3
• UNII: TC7N3T6225
• DSSTox Substance ID: DTXSID6063355
• Nikkaji Number: J8.692D
• Wikidata: Q27289887
• Mol file: 4212-43-5.mol

Synonyms:perpropionic acid;propaneperoxoic acid

Chemical Property of Peroxypropionic acid

Chemical Property:

• Vapor Pressure: 3.05mmHg at 25°C
• Refractive Index: 1.4540 (estimate)
• Boiling Point: 136.9°Cat760mmHg
• Flash Point: 58.6°C
• PSA: 46.53000
• Density: 1.139g/cm³
• LogP: 0.41260
• XLogP3: 0.1
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 90.031694049
• Heavy Atom Count: 6
• Complexity: 50

Purity/Quality:

99% ^*data from raw suppliers

PEROXYPROPIONIC ACID 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC(=O)OO

Technology Process of Peroxypropionic acid

There total 23 articles about Peroxypropionic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

→ beta-homocyclocitral + perpropionic acid (4212-43-5)

Guidance literature:

Reference yield:

propionic acid (802294-64-0,79-09-4) → perpropionic acid (4212-43-5)

Guidance literature:

With chloroform; sulfuric acid; dihydrogen peroxide; unter Entfernen des entstehenden Wassers bei vermindertem Druck;

DOI:10.1021/jo01106a001

Reference yield:

N,N'-dipropionyl-sulfamide (29824-69-9) → perpropionic acid (4212-43-5)

Guidance literature:

With sodium perborate; sodium dihydrogenphosphate; In water; pH=6.5 - 7.0;

upstream raw materials:

propionaldehyde

propionic acid

propionic acid anhydride

sulfuric acid

Downstream raw materials:

ethyl adduct of α-phenyl-N-t-butylnitrone

(α-Ethoxy)-benzyl-tert-butyl-nitroxid-Radikal

tetramethyl succinic acid

Ethyl propionate

Refernces

• 1、 Briner,Lardon. "-". . p. 852,856,1070. Retrieved 1936.
• 2、 Leveneur, Sebastien,Kumar, Narendra,Salmi, Tapio,Murzin, Dmitry Yu.. "Stability of hydrogen peroxide during perhydrolysis of carboxylic acids on acidic heterogeneous catalysts". . p. 389 - 401. Retrieved 2010.
• 3、 Hasson, Alam S.,Tyndall, Geoffrey S.,Orlando, John J.,Singh, Sukhdeep,Hernandez, Samuel Q.,Campbell, Sean,Ibarra, Yesenia. "Branching ratios for the reaction of selected carbonyl-containing peroxy radicals with hydroperoxy radicals". experimental part. p. 6264 - 6281. Retrieved 2012/08/28.