CERIUM BORIDE

Base Information

• Chemical Name: CERIUM BORIDE
• CAS No.: 12008-02-5
• Molecular Formula: B₆Ce
• Molecular Weight: 206.12
• Mol file: 12008-02-5.mol

Synonyms:Ceriumboride (CeB6) (6CI,8CI); Cerium hexaboride; Cerium hexaboride (CeB6)

Chemical Property of CERIUM BORIDE

Chemical Property:

• Melting Point: 2190°C
• PSA: 0.00000
• Density: 4.870
• LogP: -2.28480
• Water Solubility.: insoluble H2O, HCl [CRC10]

Purity/Quality:

98%,99%, ^*data from raw suppliers

CERIUM BORIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of CERIUM BORIDE

There total 18 articles about CERIUM BORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

lithium borohydride + cerium(III) fluoride (7758-88-5) → cerium hexaboride (12008-02-5) + hydrogen (1333-74-0) + diborane (19287-45-7)

Guidance literature:

In neat (no solvent); byproducts: LiF, CeH2; (LiBH4+1/3CeF3) mixt. (ball milled for 1-48 h) evacuated to 1E-3 Torr, heated at rate 2°C/min from room temp. to 450-600°C; DSC-TG-MS, XRD;

DOI:10.1016/j.jallcom.2010.09.066

Reference yield:

lithium borohydride + cerium chloride (7790-86-5,15785-07-6) → cerium hexaboride (12008-02-5) + hydrogen (1333-74-0) + diborane (19287-45-7)

Guidance literature:

In neat (no solvent); byproducts: LiCl, CeH2; (LiBH4+1/3CeCl3) mixt. (ball milled for 1-48 h) evacuated to 1E-3 Torr, heated at rate 2°C/min from room temp. to 450-600°C; DSC-TG-MS, XRD;

DOI:10.1016/j.jallcom.2010.09.066

Reference yield:

cerium(IV) oxide + sodium tetrahydroborate (16940-66-2) → cerium hexaboride (12008-02-5)

Guidance literature:

at 900 - 1200 ℃; for 2h; under 15.0015 Torr;

DOI:10.1016/j.jallcom.2014.06.207

upstream raw materials:

cerium

palladium

cerium chloride

boron trichloride

Refernces

• 1、 Torabi, Omid,Naghibi, Sanaz,Golabgir, Mohammad-Hossein,Jamshidi, Amin. "Mechanochemical Synthesis of High Crystalline Cerium Hexaboride Nanoparticles from CeO2-B2O3-Mg Ternary System". . p. 379 - 384. Retrieved 2016.
• 2、 Zhang, Maofeng,Wang, Xiaoqing,Zhang, Xianwen,Wang, Pengfei,Xiong, Shenglin,Shi, Liang,Qian, Yitai. "Direct low-temperature synthesis of RB6 (R=Ce, Pr, Nd) nanocubes and nanoparticles". . p. 3098 - 3104. Retrieved 2009.
• 3、 Sologub, Oksana,Rogl, Peter,Salamakha, Leonid,Bauer, Ernst,Hilscher, Gerfried,Michor, Herwig,Giester, Gerald. "On phase equilibria and crystal structures in the systems Ce-Pd-B and Yb-Pd-B. Physical properties of R2Pd13.6B5 (R=Yb, Lu)". . p. 1013 - 1037. Retrieved 2010.
• 4、 Sologub,Hester,Salamakha,Leroy,Godart. "Ab initio structure determination of new boride CePt3B, a distorted variant of CaTiO3". . p. 10 - 17. Retrieved 2002.
• 5、 Zhang, Han,Zhang, Qi,Tang, Jie,Qin, Lu-Chang. "Single-crystalline CeB6 nanowires". . p. 8002 - 8003. Retrieved 2005.
• 6、 Liu, Shuiqing,Wang, Xin,Cui, Chunxiang,Zhao, LiChen,Li, Nuo,Zhang, Zhe,Ding, Jinhua,Sha, Denghao. "Enhanced grain refinement of in situ CeB6/Al composite inoculant on pure aluminum by microstructure control". . p. 926 - 934. Retrieved 2017.
• 7、 Wang, Yu,Chou, Kuo-Chih,Zhang, Guo-Hua. "Preparations of lanthanum hexaboride (LaB6) and cerium hexaboride (CeB6)". . p. 1954 - 1966. Retrieved 2021/11/24.