1,3,5,7-Tetrmethyl-adamantane

Base Information

• Chemical Name: 1,3,5,7-Tetrmethyl-adamantane
• CAS No.: 1687-36-1
• Molecular Formula: C14H24
• Molecular Weight: 192.345
• Hs Code.: 2902199090
• Mol file: 1687-36-1.mol

Synonyms:1,3,5,7-Tetramethyl-adamantane;

Chemical Property of 1,3,5,7-Tetrmethyl-adamantane

Chemical Property:

• Vapor Pressure: 0.206mmHg at 25°C
• Melting Point: 65.0-66.5 °C
• Refractive Index: 1.523
• Boiling Point: 216.4 °C at 760 mmHg
• Flash Point: 77.3 °C
• PSA: 0.00000
• Density: 0.969 g/cm³
• LogP: 4.39300

Purity/Quality:

98%min ^*data from raw suppliers

1,3,5,7-TETRAMETHYLADAMANTANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,3,5,7-Tetrmethyl-adamantane

There total 46 articles about 1,3,5,7-Tetrmethyl-adamantane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1-bromo-3,5,7-trimethyladamantane (53398-55-3) + methylmagnesium bromide (75-16-1) → 1,3,5,7-tetramethyladamantane (1687-36-1)

Guidance literature:

In dibutyl ether; at 105 ℃;

Reference yield: 88.0%

tetramethylsilane (75-76-3) + 1-bromo-3,5,7-trimethyladamantane (53398-55-3) → 1,3,5,7-tetramethyladamantane (1687-36-1)

Guidance literature:

With aluminum tri-bromide; In dichloromethane; at 20 ℃; for 0.25h;

Reference yield: 79.0%

1-bromo-3,5,7-trimethyladamantane (53398-55-3) + methyl iodide (74-88-4) → 1,3,5,7-tetramethyladamantane (1687-36-1)

Guidance literature:

With magnesium; In diethyl ether; at 90 - 100 ℃; for 1h;

DOI:10.1134/S1070428021050122

upstream raw materials:

<4,4,4>propellane

1-Adamantyl bromide

tetramethylsilane

1-chloroadamantane

Refernces

• 1、 Bonsir, Maxime,Davila, Christian,Geerts, Yves,Kennedy, Alan R.. "Exhaustive One-Step Bridgehead Methylation of Adamantane Derivatives with Tetramethylsilane". supporting information. p. 5227 - 5237. Retrieved 2021/10/19.
• 2、 Molle, G.,Dubois, J. E.,Bauer, P.. "Contribution a l'etude des reactions d'alkylation et de polyalkylation de l'adamantane et de ses homologues". . p. 2428 - 2433. Retrieved 2007/10/02.