1,4'-Bipyridinium, chloride

Base Information

• Chemical Name: 1,4'-Bipyridinium, chloride
• CAS No.: 5421-92-1
• Molecular Formula: C10H9ClN2^.HCl
• Molecular Weight: 229.109
• Hs Code.: 29333990
• Mol file: 5421-92-1.mol

Synonyms:1,4'-Bipyridinium, chloride;1,4'-bipyridinium chloride;AKOS028109836;4-(pyridyl)pyridinium chloride hydrochloride;NS00044773

Chemical Property of 1,4'-Bipyridinium, chloride

Chemical Property:

• Appearance/Colour: Light brown powder
• Melting Point: 166-170 °C (dec.)(lit.)
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 16.77000
• Density: g/cm³
• LogP: -0.83570
• Storage Temp.: Inert atmosphere,Room Temperature
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 228.0221037
• Heavy Atom Count: 14
• Complexity: 124

Purity/Quality:

98% ^*data from raw suppliers

Hydron4-Pyridin-1-ium-1-ylpyridineDichloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: C,Xi
• Statements: 36/37/38-34
• Safety Statements: 26-37/39-45-36/37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=[N+](C=C1)C2=CC=[NH+]C=C2.[Cl-].[Cl-]

Technology Process of 1,4'-Bipyridinium, chloride

There total 3 articles about 1,4'-Bipyridinium, chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

pyridine (110-86-1) → 1-(4-pyridyl)pyridinium chloride hydrochloride (5421-92-1)

Guidance literature:

With thionyl chloride; for 72h; Ambient temperature;

DOI:10.1007/BF00909667

Reference yield: 52.1%

→ 1-(4-pyridyl)pyridinium chloride hydrochloride (5421-92-1)

Guidance literature:

Reference yield:

pyridine (110-86-1) + thionyl chloride (7719-09-7) → 1-(4-pyridyl)pyridinium chloride hydrochloride (5421-92-1)

Guidance literature:

upstream raw materials:

pyridine

thionyl chloride

Downstream raw materials:

4-(3-nitrophenoxy)pyridine

4-(2-nitro-phenoxy)-pyridine

4-ethoxythiocarbonylmercapto-1-methyl-pyridinium; methyl sulfate

4-(toluene-4-sulfonyl)-pyridine

Refernces

• 1、 Cornella, Josep,Faber, Teresa,Gómez-Palomino, Alejandro,Ghiazza, Clément. "Deaminative chlorination of aminoheterocycles". . . Retrieved 2021/12/23.
• 2、 -. "Process for producing 4-dimethyl amino pyridine (4-DMAP)". Page 2. . Retrieved 2008/06/13.