9-hydroxybimol.cyclic ester ;;

Base Information

• Chemical Name: 9-hydroxybimol.cyclic ester
• CAS No.: 797-29-5
• Molecular Formula: C₁₈H₃₂O₄
• Molecular Weight: 312.45
• Mol file: 797-29-5.mol

Synonyms:

Chemical Property of 9-hydroxybimol.cyclic ester ;;

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 9-hydroxybimol.cyclic ester ;;

There total 3 articles about 9-hydroxybimol.cyclic ester ;; which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

9-hydroxynonanoic acid (3788-56-5) → 1,11-dioxacycloisocosane (797-29-5) + oxecan-2-one (6008-27-1)

Guidance literature:

With p-nitrobenzoic anhydride; scandium tris(trifluoromethanesulfonate); In tetrahydrofuran; acetonitrile; for 5h; Yields of byproduct given; Heating;

DOI:10.1021/jo952237x

Reference yield: 74.0%

acrylic acid-6-iodohexyl ester (133122-99-3) → n-hexyl acrylate (2499-95-8,27103-47-5) + 1,11-dioxacycloisocosane (797-29-5) + oxecan-2-one (6008-27-1)

Guidance literature:

With sodium cyanoborohydride; In methanol; for 3h; Yields of byproduct given; Ambient temperature; Irradiation;

DOI:10.1246/cl.1994.1789

Reference yield:

9-hydroxynonanoic acid (3788-56-5) → 1,11-dioxacycloisocosane (797-29-5)

Guidance literature:

With benzenesulfonic acid; benzene;

DOI:10.1002/hlca.193501801153

upstream raw materials:

9-hydroxynonanoic acid

acrylic acid-6-iodohexyl ester

Refernces

• 1、 Abraham, Sinoj,Narine, Suresh S.. "A facile synthesis of lipid stabilized gold nanoparticles: A step towards biodegradable biosensors". body text. p. 7027 - 7032. Retrieved 2012/05/20.
• 2、 Abe, Motoji,Hayashikoshi, Takaoki,Kurata, Takeo. "A New Synthetic Method of Macrocyclic Lactones from ω-Iodoalkylacrylates". . p. 1789 - 1792. Retrieved 2007/10/02.