(S)-CYCLOHEX-2-ENYLAMINE, 95%, (98% E.E.)

Base Information

• Chemical Name: (S)-CYCLOHEX-2-ENYLAMINE, 95%, (98% E.E.)
• CAS No.: 153922-89-5
• Molecular Formula: C6H11 N
• Molecular Weight: 97.15824
• Mol file: 153922-89-5.mol

Synonyms:2-Cyclohexen-1-amine,(S)-; (S)-2-Cyclohexen-1-amine

Chemical Property of (S)-CYCLOHEX-2-ENYLAMINE, 95%, (98% E.E.)

Chemical Property:

• Vapor Pressure: 8.425mmHg at 25°C
• Refractive Index: 1.4440 (estimate)
• Boiling Point: 133.55°C at 760 mmHg
• PKA: 10.31±0.20(Predicted)
• Flash Point: 33.018°C
• PSA: 26.02000
• Density: 0.8640 (rough estimate)
• LogP: 1.75410

Purity/Quality:

99% ^*data from raw suppliers

(S)-CYCLOHEX-2-ENYLAMINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R34:Causes burns.
• Hazard Codes: C:Corrosive
• Statements: R34:Causes burns.
• Safety Statements: S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.; S36/37/39:Wear suitabl

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (S)-CYCLOHEX-2-ENYLAMINE, 95%, (98% E.E.)

There total 2 articles about (S)-CYCLOHEX-2-ENYLAMINE, 95%, (98% E.E.) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(S)-N,N-bis-p-methoxybenzyl(cyclohex-2-enyl)amine (656223-61-9) → (S)-(cyclohex-2-enyl)amine (153922-89-5)

Guidance literature:

With ammonium cerium(IV) nitrate; In ethanol; water; at 20 ℃; for 1h;

DOI:10.1021/ol036264i

Reference yield:

cyclohex-2-enyl methyl carbonate (58329-99-0) → (S)-(cyclohex-2-enyl)amine (153922-89-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 3-(2Ph2PC6H4)-2-[4-(PSPEGNHCO(CH2)3)C6H4]5HIm[1,5-a]In-2-one / [PdCl(η³-C3H5)]2 / H2O / 24 h / 25 °C

2: CAN / ethanol; H₂O / 1 h / 20 °C

With ammonium cerium(IV) nitrate; 3-(2Ph₂PC₆H₄)-2-[4-(PSPEGNHCO(CH₂)3)C₆H₄]5HIm[1,5-a]In-2-one; bis(η3-allyl-μ-chloropalladium(II)); In ethanol; water;

DOI:10.1021/ol036264i

Reference yield:

benzyl bromide (100-39-0) + (S)-(cyclohex-2-enyl)amine (153922-89-5) → (S)-N,N-dibenzyl(cyclohex-2-enyl)amine

Guidance literature:

With potassium carbonate; In methanol; dichloromethane; water; for 1h;

DOI:10.1021/ol036264i

upstream raw materials:

(S)-N,N-bis-p-methoxybenzyl(cyclohex-2-enyl)amine

cyclohex-2-enyl methyl carbonate

Refernces