Zinc, [ethanedioato(2-)-kappaO1,kappaO2]-

Base Information

• Chemical Name: Zinc, [ethanedioato(2-)-kappaO1,kappaO2]-
• CAS No.: 547-68-2
• Deprecated CAS: 112901-80-1,116295-84-2,1430716-13-4,116295-84-2
• Molecular Formula: C2H2O4Zn
• Molecular Weight: 153.41
• Hs Code.: 2917119000
• European Community (EC) Number: 208-934-2
• DSSTox Substance ID: DTXSID1074917
• Mol file: 547-68-2.mol

Synonyms:ZINC OXALATE;547-68-2;EINECS 208-934-2;UNII-F4068O7XQF;Zinc, [ethanedioato(2-)-.kappa.O1,.kappa.O2]-;oxalic acid;zinc;Zinc oxalate hydrate;Zinc, [ethanedioato(2-)-kappaO1,kappaO2]-;C2H2O4.Zn;C2-H2-O4.Zn;F4068O7XQF;Zinc, (ethanedioato(2-)-kappaO1,kappaO2)-;DTXSID1074917;NSC 85548

Chemical Property of Zinc, [ethanedioato(2-)-kappaO1,kappaO2]-

Chemical Property:

• Vapor Pressure: 2.51E-06mmHg at 25°C
• Boiling Point: 365.1 °C at 760mmHg
• Flash Point: 188.8 °C
• PSA: 74.60000
• LogP: -0.84690
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 153.924450
• Heavy Atom Count: 7
• Complexity: 75.7

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Metals, Organic Compounds
• Canonical SMILES: C(=O)(C(=O)O)O.[Zn]

Technology Process of Zinc, [ethanedioato(2-)-kappaO1,kappaO2]-

There total 40 articles about Zinc, [ethanedioato(2-)-kappaO1,kappaO2]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

ZnCl2(bis(4-nitrophenyl)acenaphthenequinonediimine) + potassium oxalate (583-52-8) → bis(4-nitrophenyl)acenaphthenequinonediimine (444798-17-8) + zinc(II) oxalate (547-68-2)

Guidance literature:

In dichloromethane; water; Zn complex was suspended in CH2Cl2 and soln. potassium oxalate in water was added, shaked for 5 min;

DOI:10.1021/om020147u

Reference yield: 85.0%

[ZnCl2(bis(3,5-dichlorophenyl)acenaphthenequinonediimine)] (845834-87-9) + potassium oxalate (583-52-8) → bis(3,5-dichlorophenyl)acenaphthenequinonediimine (357981-03-4) + zinc(II) oxalate (547-68-2)

Guidance literature:

In dichloromethane; water; Zn complex was suspended in CH2Cl2 and soln. potassium oxalate in water was added, shaked for 5 min;

DOI:10.1021/om020147u

Reference yield: 85.0%

ZnCl2(bis(3-trifluoromethylphenyl)acenaphthenequinonediimine) + potassium oxalate (583-52-8) → bis(3-trifluoromethylphenyl)acenaphthenequinonediimine (444798-19-0) + zinc(II) oxalate (547-68-2)

Guidance literature:

In dichloromethane; water; Zn complex was suspended in CH2Cl2 and soln. potassium oxalate in water was added, shaked for 5 min;

DOI:10.1021/om020147u

upstream raw materials:

oxalic acid

[Zn(II)(2,2'-bipyridine)(oxalato)]

zinc(II) carbonate

oxalic acid dihydrate

Downstream raw materials:

carbon dioxide

carbon monoxide

pyrographite

zinc(II) cyanimide

Refernces

• 1、 Xu, Congkang,Xu, Guoding,Liu, Yingkai,Wang, Guanghou. "A simple and novel route for the preparation of ZnO nanorods". . p. 175 - 179. Retrieved 2002.
• 2、 Czakis-Sulikowska,Malinowska,Markiewicz. "Synthesis and thermal decomposition of new complexes of bipyridine isomers with zinc(II) and cadmium(II) oxalates". . p. 151 - 156. Retrieved 2000.
• 3、 Diodati, Stefano,Hennemann, J?rg,Fresno, Fernando,Gialanella, Stefano,Dolcet, Paolo,Lavren?i? ?tangar, Ur?ka,Smarsly, Bernd M.,Gross, Silvia. "Easy and Green Route towards Nanostructured ZnO as an Active Sensing Material with Unexpected H2S Dosimeter-Type Behaviour". . p. 837 - 846. Retrieved 2019.
• 4、 Remias, Robert,Kukovecz, Akos,Daranyi, Maria,Kozma, Gabor,Varga, Szilvia,Konya, Zoltan,Kiricsi, Imre. "Synthesis of zinc glycerolate microstacks from a ZnO nanorod sacrificial template". . p. 3622 - 3627. Retrieved 2009.
• 5、 Kaur, Japinder,Bansal,Singhal, Sonal. "Photocatalytic degradation of methyl orange using ZnO nanopowders synthesized via thermal decomposition of oxalate precursor method". . p. 33 - 38. Retrieved 2013.
• 6、 Krishnan, K.,Ninan, K. N.,Madhusudanan, P. M.. "". . p. 295 - 306. Retrieved 1985.
• 7、 Dhatshanamurthi, P.,Jayamoorthy, K.,Sasikala, R.,Shanthi, M.,Subash, B.,Vijaya, P.. "Superficial sonication synthesis of a highly sunshine active metal modified ZnO photocatalyst and its multiple applications". . . Retrieved 2021/09/28.