Sodium;tri(butan-2-yl)boranuide

Base Information

• Chemical Name: Sodium;tri(butan-2-yl)boranuide
• CAS No.: 67276-04-4
• Molecular Formula: C12H27BNa
• Molecular Weight: 206.155
• Hs Code.: 29319090
• Mol file: 67276-04-4.mol

Synonyms:sodium;tri(butan-2-yl)boranuide;JUFGMKFPFVIKOY-UHFFFAOYSA-N

Chemical Property of Sodium;tri(butan-2-yl)boranuide

Chemical Property:

• Flash Point: 5 °F
• PSA: 0.00000
• Density: 0.893 g/mL at 25 °C(lit.)
• LogP: 4.61380
• Storage Temp.: Flammables + water-Freezer (-20°C)e area
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 6
• Exact Mass: 206.2181753
• Heavy Atom Count: 14
• Complexity: 104

Purity/Quality:

98%,99%, ^*data from raw suppliers

N-SelectrideSolution(1.0?MinTHF) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,C
• Hazard Codes: F,C
• Statements: 11-14/15-19-22-34-37-40
• Safety Statements: 16-26-27-36/37/39-45-43

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [BH-](C(C)CC)(C(C)CC)C(C)CC.[Na+]
• Uses: Reducing agent Reactant for: Conjugate hydride reduction-initiated tandem cyclization reactions Sereoselective nucleophilic addition reactions. Reducing agentReactant for:Conjugate hydride reduction-initiated tandem cyclization reactionsSereoselective nucleophilic addition reactions

Technology Process of Sodium;tri(butan-2-yl)boranuide

There total 4 articles about Sodium;tri(butan-2-yl)boranuide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

tri(sec-butyl)borane (1113-78-6) + hydrogen (1333-74-0) + sodium (7440-23-5) → sodium tri-sec-butylborohydride (67276-04-4)

Guidance literature:

hydrogen; sodium; iron(III) chloride; naphthalene; In tetrahydrofuran; at 100 - 110 ℃;

tri(sec-butyl)borane; In tetrahydrofuran; at 20 - 30 ℃; for 1h;

Reference yield: 57.0%

sodium-potassium + tri(sec-butyl)borane (1113-78-6) + hydrogen (1333-74-0) → sodium tri-sec-butylborohydride (67276-04-4) + potassium tri-sec-butyl-borohydride

Guidance literature:

In tetrahydrofuran; at 42 - 85 ℃; under 2585.81 Torr; Reactivity;

Reference yield:

tri(sec-butyl)borane (1113-78-6) + sodium aluminum diethyl dihydride → 1,4-diazabicyclo{2.2.2}octane * AlH3 + sodium tri-sec-butylborohydride (67276-04-4)

Guidance literature:

With 1,4-diazabicyclo{2.2.2}octane; In tetrahydrofuran; toluene; sodium diethyldihydroaluminate soln. in toluene was added to THF soln. of trialkylborane in presence of 1,4-diazabicyclo(2.2.2)octane, white pptn. of AlH3-adduct was filtered off; detected by (11)B-NMR in the filtrate;

DOI:10.1039/c39890001639

upstream raw materials:

tri(sec-butyl)borane

hydrogen

sodium

Downstream raw materials:

difluorophosphine

phosphan

trifluorophosphane

tri(sec-butyl)borane

Refernces

• 1、 -. "SYNTHESIS OF ALKALI METAL SUBSTITUTED BOROHYDRIDE REAGENTS". Page 12. . Retrieved 2010/02/08.
• 2、 -. "Method of synthesis of alkali metal trisubstituted borohydride reagents". . . Retrieved 2008/06/13.