1,1-Dimethoxynonane

Base Information

• Chemical Name: 1,1-Dimethoxynonane
• CAS No.: 18824-63-0
• Molecular Formula: C11H24O2
• Molecular Weight: 188.31
• Hs Code.: 2911000000
• European Community (EC) Number: 242-603-3
• UNII: R293HT233N
• DSSTox Substance ID: DTXSID8066424
• Nikkaji Number: J222.318J
• Wikidata: Q27287701
• Metabolomics Workbench ID: 46386
• Mol file: 18824-63-0.mol

Synonyms:1,1-Dimethoxynonane;18824-63-0;Nonanal dimethyl acetal;Nonane, 1,1-dimethoxy-;1,1-dimethoxy-nonane;n-Nonanal dimethyl acetal;UNII-R293HT233N;Pelargonaldehyde Dimethyl Acetal;R293HT233N;EINECS 242-603-3;AI3-36124;1,1-Dimethoxynonane #;1,1-Dimethoxynonane, 9CI;SCHEMBL873446;Nonyl Aldehyde Dimethyl Acetal;NONANAL, DIMETHYL ACETAL;DTXSID8066424;FEMA NO. 4367;CHEBI:183015;MFCD00036646;AKOS006275074;NONANAL DIMETHYL ACETAL [FHFI];AS-57744;PELARGONIC ALDEHYDE DIMETHYL ACETAL;CS-0152271;FT-0690784;N0915;D97662;Q27287701

Chemical Property of 1,1-Dimethoxynonane

Chemical Property:

• Vapor Pressure: 0.235mmHg at 25°C
• Refractive Index: 1.419
• Boiling Point: 213.8 °C at 760 mmHg
• Flash Point: 55.3 °C
• PSA: 18.46000
• Density: 0.843 g/cm³
• LogP: 3.35590
• XLogP3: 4.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 9
• Exact Mass: 188.177630004
• Heavy Atom Count: 13
• Complexity: 90.1

Purity/Quality:

98%,99%, ^*data from raw suppliers

Nonanal Dimethyl Acetal >97.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCC(OC)OC

Technology Process of 1,1-Dimethoxynonane

There total 37 articles about 1,1-Dimethoxynonane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

methanol (67-56-1) + nonan-1-al (124-19-6) → 1,1-dimethoxynonane (18824-63-0)

Guidance literature:

With ammonia; titanium tetrachloride; In dichloromethane; at 0 ℃; Product distribution; other reagent (Et₃N);

DOI:10.1016/S0040-4020(98)00982-X

Reference yield: 92.0%

nonan-1-al (124-19-6) + trimethyl orthoformate (149-73-5) → 1,1-dimethoxynonane (18824-63-0)

Guidance literature:

With lithium tetrafluoroborate; In methanol; for 2h; Inert atmosphere; Reflux;

DOI:10.1055/s-0035-1560380

Reference yield: 84.0%

methanol (67-56-1) + 1-phenylthio-1-trimethylsilylnonane (75340-08-8) → 1,1-dimethoxynonane (18824-63-0)

Guidance literature:

With tetraethylammonium tosylate; carbon rod anode, carbon rod cathode (i.d. 2 mm); constant current: 10 mA; electricity 4.13 F/mol;

DOI:10.1016/S0040-4020(01)87051-4

upstream raw materials:

methanol

nonan-1-al

2-phenylsulfanyl-decanoic acid

1,1-bis-methylsulfanyl-nonane

Downstream raw materials:

1-methoxy-1-phenylthiononane

1-benzylthio-1-methoxynonane

C₂₃H₃₂S₂

C₈H₁₇CH(SC₆H₅)2

Refernces

• 1、 Jin, Xin,Zhao, Kun,Kong, Fangfang,Cui, Feifei,Liu, Qiangqiang,Zhang, Yaowu. "The mechanism of acetal formation in acid-free rh-catalyzed tandem hydroformylation-acetalization of olefins in MeOH". . p. 192 - 196. Retrieved 2014.
• 2、 -. "Green synthesis method of acetal-type or ketal-type compound". Paragraph 0069-0074. . Retrieved 2017/05/26.