Nitrogen-15

Base Information

• Chemical Name: Nitrogen-15
• CAS No.: 14390-96-6
• Molecular Formula: N
• Molecular Weight: 18.0238
• European Community (EC) Number: 685-217-4
• DSSTox Substance ID: DTXSID80929866
• Nikkaji Number: J453.192B
• Wikidata: Q82905006
• Mol file: 14390-96-6.mol

Synonyms:15N isotope;N-15 isotope;Nitrogen-15

Chemical Property of Nitrogen-15

Chemical Property:

• PSA: 3.24000
• LogP: 0.32390
• XLogP3: -0.7
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 18.023583994
• Heavy Atom Count: 1
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: N
• Isomeric SMILES: [15NH3]

Technology Process of Nitrogen-15

There total 43 articles about Nitrogen-15 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

urea-15N2 (2067-80-3) + oxygen (80937-33-3) + Nitrogen dioxide (10102-44-0) → isocyanic acid (75-13-8) + isocyanic acid (37828-16-3) + carbon dioxide (124-38-9,18923-20-1) + nitrogen(II) oxide (10102-43-9) + ammonia (14390-96-6,13767-16-3)

Guidance literature:

With NaY zeolite; In neat (no solvent); carbamide was absorbed on NaY zeolite, 0.5 Torr NO2 was equilibrated for30 min at room temp.; H2O and (15)NNO were also formed; heating up to 4 73 K; monitored and detected by IR in solid and gas-phase;

DOI:10.1016/j.jcat.2005.06.025

Reference yield:

15N-hydroxylamine (72960-76-0) → ammonia (14390-96-6,13767-16-3) + hydrazine (302-01-2,78206-91-4,119775-10-9,75013-58-0)

Guidance literature:

With Na₃[Fe(CN)5NH₃]*3H₂O; In water-d2; (Ar); at pH ca. 9; not isolated, detected by NMR;

DOI:10.1021/ja046724i

Reference yield:

hydrogen (1333-74-0) + C24H42Fe2(15)NS2(1+)*C24H20B(1-) → ammonia (14390-96-6,13767-16-3) + C24H20B(1-)*H(1+)*H3(15)N + C26H45Fe2S3(1+)*C24H20B(1-)

Guidance literature:

at 20 ℃; for 12h; under 15201 Torr; Autoclave;

DOI:10.1038/s41557-021-00852-6

upstream raw materials:

nitrogen

hydrogen

urea-15N₂

oxygen

Downstream raw materials:

⁽¹⁵⁾N-nitrous oxide

⁽¹⁴⁾-nitrogen

dinitrogen

{Pt(⁽¹⁵⁾NSO)2(P(CH₃)2(C₆H₅))2}

Refernces

• 1、 Rumpel, Helmut,Limbach, Hans-Heinrich. "NMR Study of Kinetic HH/HD/DD Isotope, Solvent, and Solid-State Effects on the Double Proton Transfer in Azophenine". . p. 5429 - 5441. Retrieved 1989.
• 2、 Chen, Zhen,Li, Junhua,Li, Yadong,Peng, Yue,Xiong, Shangchao,Yamashita, Hiromi,Yin, Haibo. "Dual Active Centers Bridged by Oxygen Vacancies of Ruthenium Single-Atom Hybrids Supported on Molybdenum Oxide for Photocatalytic Ammonia Synthesis". supporting information. . Retrieved 2022/02/17.
• 3、 Cheng, Xiyue,Deng, Shuiquan,Fu, Xianzhi,Guo, Binbin,Guo, Wei,Tang, Yu,Wu, Ling. "Dehydrated UiO-66(SH)2: The Zr?O Cluster and Its Photocatalytic Role Mimicking the Biological Nitrogen Fixation". supporting information. . Retrieved 2022/02/17.