1-Chloroundecane

Base Information

• Chemical Name: 1-Chloroundecane
• CAS No.: 2473-03-2
• Molecular Formula: C11H23Cl
• Molecular Weight: 190.757
• Hs Code.: 2903199000
• European Community (EC) Number: 219-596-0
• NSC Number: 70016
• UNII: 6U47K7QVJ6
• DSSTox Substance ID: DTXSID8062448
• Nikkaji Number: J591F
• Wikidata: Q69757759
• Mol file: 2473-03-2.mol

Synonyms:1-CHLOROUNDECANE;2473-03-2;Undecane, 1-chloro-;Undecyl chloride;n-Undecyl chloride;1-chloro-undecane;NSC-70016;SCHEMBL969269;6U47K7QVJ6;DTXSID8062448;NSC70016;EINECS 219-596-0;MFCD00040870;NSC 70016;AKOS009159400;BS-22118;AI3-08977;D89276;EN300-674738

Chemical Property of 1-Chloroundecane

Chemical Property:

• Vapor Pressure: 0.0523mmHg at 25°C
• Melting Point: -16.9°C
• Refractive Index: 1.4380-1.4410
• Boiling Point: 242°C
• Flash Point: 94.4°C
• PSA: 0.00000
• Density: 0,87 g/cm3
• LogP: 4.75600
• XLogP3: 6.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 9
• Exact Mass: 190.1488284
• Heavy Atom Count: 12
• Complexity: 71.4

Purity/Quality:

98%,99%, ^*data from raw suppliers

1-Chloroundecane ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCCCl

Technology Process of 1-Chloroundecane

There total 26 articles about 1-Chloroundecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

11-chloroundec-1-ene (872-17-3) → 1-chloroundecane (2473-03-2)

Guidance literature:

With ethanol; (^BQ?NC^OP)IrHCl; sodium t-butanolate; at 60 ℃; for 2h; Inert atmosphere; Schlenk technique; Sealed tube;

DOI:10.1021/jacs.8b01038

Reference yield: 96.0%

undecyl alcohol (112-42-5) → 1-chloroundecane (2473-03-2)

Guidance literature:

With N,N-diphenylchloromethyleneiminium chloride; triethylamine; In dichloromethane; for 3h; Ambient temperature;

DOI:10.1246/cl.1984.1173

Reference yield: 89.0%

1-undecylpiperidine (24935-28-2) → 1-chloroundecane (2473-03-2)

Guidance literature:

With phenyl chloroformate; In benzene; Heating;

DOI:10.1016/S0040-4039(00)95746-0

upstream raw materials:

n-Undecane

undecyl alcohol

1-undecylpiperidine

C₁₇H₂₈Cl₂Te

Downstream raw materials:

undecyl alcohol

1-fluoroundecane

1-undecene

1-undecylamine

Refernces

• 1、 -. "PROCESS FOR THE PREPARATION OF ORGANIC HALIDES". Paragraph 00162. . Retrieved 2017/08/01.
• 2、 Khusnutdinov,Shchadneva,Burangulova,Muslimov,Dzhemilev. "Oxidation of monohydric and dihydric alcohols with CCl4 catalyzed by molybdenum compounds". . p. 1615 - 1621. Retrieved 2007/10/03.