2-(METHYLTHIO)PHENYL ISOTHIOCYANATE

Base Information

• Chemical Name: 2-(METHYLTHIO)PHENYL ISOTHIOCYANATE
• CAS No.: 51333-75-6
• Molecular Formula: C8H7 N S2
• Molecular Weight: 181.282
• Hs Code.: 2930909090
• Mol file: 51333-75-6.mol

Synonyms:2-(Methylthio)isothiocyanatobenzene;2-(Methylthio)phenyl isothiocyanate

Chemical Property of 2-(METHYLTHIO)PHENYL ISOTHIOCYANATE

Chemical Property:

• Vapor Pressure: 0.00356mmHg at 25°C
• Refractive Index: n20/D 1.695(lit.)
• Boiling Point: 149-150 °C10 mm Hg(lit.)
• Flash Point: >230 °F
• PSA: 69.75000
• Density: 1.227 g/mL at 25 °C(lit.)
• LogP: 3.14280
• Sensitive.: Moisture Sensitive

Purity/Quality:

98%Min ^*data from raw suppliers

2-(Methylthio)phenylIsothiocyanate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): 3243502
• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-27-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of 2-(METHYLTHIO)PHENYL ISOTHIOCYANATE

There total 2 articles about 2-(METHYLTHIO)PHENYL ISOTHIOCYANATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

2-(Methylthio)aniline (2987-53-3) + di-2-pyridyl thionocarbonate (96989-50-3) → 1-isothiocyanato-2-(methylthio)benzene (51333-75-6)

Guidance literature:

In dichloromethane; at 20 ℃; for 67h; Inert atmosphere;

DOI:10.1002/cmdc.201800348

Reference yield:

N,N'-bis-(2-methylsulfanyl-phenyl)-thiourea (39794-45-1) → 1-isothiocyanato-2-(methylthio)benzene (51333-75-6) + 2-(Methylthio)aniline (2987-53-3)

Guidance literature:

bei der Destillation;

Reference yield: 99.0%

1-isothiocyanato-2-(methylthio)benzene (51333-75-6) → (2-methylsulfanyl-phenyl)-thiourea (59084-10-5)

Guidance literature:

With ammonia; In 1,2-dimethoxyethane;

DOI:10.1055/s-0031-1290963

upstream raw materials:

N,N'-bis-(2-methylsulfanyl-phenyl)-thiourea

2-(Methylthio)aniline

di-2-pyridyl thionocarbonate

Downstream raw materials:

(2-methylsulfanyl-phenyl)-thiourea

Ethyl 2-({3-[2-(methylsulfanyl)phenyl]-4,5-dioxo-2-thioxo-1-imidazolidinyl}oxy)acetate

5'-deoxy-5'-{[2-(methylthio)anilinothiocarbonyl]amino}thymidine

(7-chloro-thiazolo[5,4-d]pyrimidin-2-yl)-(2-methylsulfanyl-phenyl)-amine

Refernces