Europium nitride

Base Information

• Chemical Name: Europium nitride
• CAS No.: 12020-58-5
• Molecular Formula: EuN₀
• Molecular Weight: 165.126
• European Community (EC) Number: 234-659-2
• Mol file: 12020-58-5.mol

Synonyms:Europium nitride;azanylidyneeuropium;12020-58-5;Europium nitride (EuN);EINECS 234-659-2;Eu-N;MFCD00673096

Chemical Property of Europium nitride

Chemical Property:

• PSA: 23.79000
• Density: 8.700
• LogP: 0.01508
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 166.92431
• Heavy Atom Count: 2
• Complexity: 10

Purity/Quality:

98%,99%, ^*data from raw suppliers

Europium nitride (99.9%-Eu) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Rare Earth Metals
• Canonical SMILES: N#[Eu]

Technology Process of Europium nitride

There total 14 articles about Europium nitride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

Eu(2+)*(x)H3N*2N3(1-) → europium nitride (12020-58-5)

Guidance literature:

at 200 - 230 ℃; Inert atmosphere; Schlenk technique;

DOI:10.1002/ejic.201600709

Reference yield:

europium + sodium azide → europium nitride (12020-58-5) + sodium (7440-23-5)

Guidance literature:

In neat (no solvent); (Ar); stoich. mixt. of elements and NaN3 sealed in cleaned Nb ampoule, arc-welded ampoule enclosed in evac. silica tube, heated within 24 h to 800, 1000, or 1200°C, kept at this temp. for 3 d, cooled to room temp. in furnace; with unreacted Eu at reaction temp. of 800°C; detn. by XRD;

DOI:10.1016/j.jallcom.2004.04.082

Reference yield:

europium + sodium azide + magnesium (7439-95-4) → europium nitride (12020-58-5) + magnesium nitride + sodium (7440-23-5)

Guidance literature:

In neat (no solvent); (Ar); stoich. mixt. of elements and NaN3 sealed in cleaned Nb ampoule, arc-welded ampoule enclosed in evac. silica tube, heated within 24 h to 800°C, kept at this temp. for 3 d, cooled to room temp. in furnace; with unreacted Eu; detn. by XRD;

DOI:10.1016/j.jallcom.2004.04.082

upstream raw materials:

magnesium

nitrogen

ammonia

europium(III) chloride

Refernces

• 1、 Liu, Xiaolang,Song, Zhen,Kong, Yuwei,Wang, Shuxin,Zhang, Shiyou,Xia, Zhiguo,Liu, Quanlin. "Effects of full-range Eu concentration on Sr2-2xEu2xSi5N8 phosphors: A deep-red emission and luminescent thermal quenching". . p. 1069 - 1077. Retrieved 2019.
• 2、 Li,De With,Hintzen. "Synthesis, structure, and luminescence properties of Eu2+ and Ce3+ activated BaYSi4N7". . p. 1 - 11. Retrieved 2004.
• 3、 Müller, Thomas G.,Mogk, Jochen,Conrad, Matthias,Kraus, Florian. "Octaammine EuIIand YbIIAzides and Their Thermal Decompositions to the Nitrides". . p. 4162 - 4169. Retrieved 2016.
• 4、 Wang, Ting,Xiang, Qianchuan,Xia, Zhiguo,Chen, Jun,Liu, Quanlin. "Evolution of Structure and Photoluminescence by Cation Cosubstitution in Eu2+-Doped (Ca1-xLix)(Al1-xSi1+x)N3 Solid Solutions". . p. 2929 - 2933. Retrieved 2016.
• 5、 Li,de With,Hintzen. "The effect of replacement of Sr by Ca on the structural and luminescence properties of the red-emitting Sr2Si5N8:Eu2+ LED conversion phosphor". . p. 515 - 524. Retrieved 2008.
• 6、 Ruan, Jian,Xie, Rong-Jun,Hirosaki, Naoto,Takeda, Takashi. "Nitrogen gas pressure synthesis and photoluminescent properties of orange-red SrAlSi4N7:Eu2+ phosphors for white light-emitting diodes". . p. 536 - 542. Retrieved 2011.
• 7、 Uheda,Hirosaki,Yamamoto. "Host lattice materials in the system Ca3N 2-AlN-Si3N4 for white light emitting diode". . p. 2712 - 2717. Retrieved 2006.
• 8、 Li,Fang,Fang,Delsing,de With,Hintzen. "Electronic structure and photoluminescence properties of Eu2+-activated Ca2BN2F". . p. 3299 - 3304. Retrieved 2009.
• 9、 Imamura,Sakata,Nuruyu,Imahashi. "Preparation and properties of nanocrystalline ytterbium and europium nitride (YbN and EuN)". . p. 251 - 254. Retrieved 2006.
• 10、 Dierkes, Tobias,Plewa, Julian,Jüstel, Thomas. "From metals to nitrides - Syntheses and reaction details of binary rare earth systems". . p. 291 - 302. Retrieved 2017.