Tetradecylpyridinium bromide

Base Information

• Chemical Name: Tetradecylpyridinium bromide
• CAS No.: 1155-74-4
• Deprecated CAS: 50958-02-6
• Molecular Formula: C19H34BrN
• Molecular Weight: 356.39
• Hs Code.: 2933399090
• European Community (EC) Number: 214-586-2
• NSC Number: 148339
• UNII: V2WIJ52V0W
• DSSTox Substance ID: DTXSID5042459
• Wikidata: Q27291460
• ChEMBL ID: CHEMBL3181920
• Mol file: 1155-74-4.mol

Synonyms:C14PB cpd;tetradecylpyridinium bromide

Chemical Property of Tetradecylpyridinium bromide

Chemical Property:

• Melting Point: 65-67 °C
• PSA: 3.88000
• LogP: 2.67920
• Storage Temp.: Sealed in dry,Room Temperature
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 13
• Exact Mass: 355.18746
• Heavy Atom Count: 21
• Complexity: 184

Purity/Quality:

98%,99%, ^*data from raw suppliers

1-Tetradecylpyridin-1-ium bromide 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCCCCC[N+]1=CC=CC=C1.[Br-]

Technology Process of Tetradecylpyridinium bromide

There total 1 articles about Tetradecylpyridinium bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

pyridine (110-86-1) + 1-Bromotetradecane (112-71-0) → N-tetradecylpyridinium bromide (1155-74-4)

Guidance literature:

In ethanol; for 40h; Reflux;

DOI:10.3390/molecules15031967

Reference yield:

N-tetradecylpyridinium bromide (1155-74-4) → tetradecylpyridinium chloride (2785-54-8)

Guidance literature:

With sodium chloride; ion-exchange;

DOI:10.1021/j100307a022

Reference yield:

sodium salicylate (54-21-7) + N-tetradecylpyridinium bromide (1155-74-4) → Tetradecylpyridinium salicylate (94070-50-5)

Guidance literature:

In water; for 48h;

upstream raw materials:

pyridine

1-Bromotetradecane

Downstream raw materials:

Tetradecylpyridinium salicylate

tetradecylpyridinium chloride

Refernces

• 1、 Lang, Jacques,Zana, Raoul. "Effect of Alcohols and Oils on the Kinetics of Micelle Formation-Breakdown in Aqueous Solutions of Ionic Surfactants". . p. 5258 - 5265. Retrieved 1986.
• 2、 Bag, Santanu,Kanatzidis, Mercouri G.. "Importance of solution equilibria in the directed assembly of metal chalcogenide mesostructures". . p. 8366 - 8376. Retrieved 2008.
• 3、 Wankowski, James L.,Kaul, Michael J.,Dietz, Mark L.. "Micelle formation as a factor influencing the mode(s) of metal ion partitioning into: N -alkylpyridinium-based ionic liquids (ILs): Implications for the design of IL-based extraction systems". supporting information. p. 5674 - 5682. Retrieved 2017/12/06.
• 4、 Marek, Jan,Stodulka, Petr,Cabal, Jiri,Soukup, Ondrej,Pohanka, Miroslav,Korabecny, Jan,Musilek, Kamil,Kuca, Kamil. "Preparation of the pyridinium salts differing in the length of the N-alkyl substituent". experimental part. p. 1967 - 1972. Retrieved 2010/09/08.