Triphenylbismuth dichloride

Base Information

• Chemical Name: Triphenylbismuth dichloride
• CAS No.: 594-30-9
• Molecular Formula: C₁₈H₁₅BiCl₂
• Molecular Weight: 511.204
• European Community (EC) Number: 640-390-5
• NSC Number: 173027
• DSSTox Substance ID: DTXSID1042499
• Wikidata: Q27117071
• Mol file: 594-30-9.mol

Synonyms:TPBC compound;triphenylbismuthdichloride

Chemical Property of Triphenylbismuth dichloride

Chemical Property:

• Melting Point: 128-142 °C
• PSA: 0.00000
• LogP: 5.83940
• Storage Temp.: Refrigerator
• Solubility.: soluble in Tetrahydrofuran
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 510.03548
• Heavy Atom Count: 21
• Complexity: 285

Purity/Quality:

98%,99%, ^*data from raw suppliers

Triphenylbismuth Dichloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 20/21/22-36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Bi](C2=CC=CC=C2)(C3=CC=CC=C3)(Cl)Cl

Technology Process of Triphenylbismuth dichloride

There total 36 articles about Triphenylbismuth dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

sulfuryl dichloride (7791-25-5) + triphenylbismuthane (603-33-8) → triphenyl bismuth (2+); dichloride (507233-69-4,594-30-9,28719-54-2)

Guidance literature:

In dichloromethane; at 20 ℃; for 1h;

DOI:10.1002/chem.201604914

Reference yield: 96.0%

triphenylbismuthane (603-33-8) → triphenyl bismuth (2+); dichloride (507233-69-4,594-30-9,28719-54-2)

Guidance literature:

With samarium diiodide; In tetrahydrofuran; for 30 min at 0°C;

DOI:10.1021/ja000479v

Reference yield: 90.0%

triphenylbismuth diformate (153289-73-7) → triphenyl bismuth (2+); dichloride (507233-69-4,594-30-9,28719-54-2)

Guidance literature:

With NaCl; In water; benzene; aq. NaCl soln. added in ecxess to soln. of the diformate in benzene; vigorous stirring for 10 min; sepn. of organic layer; drying (MgSO4); evapn. under reduced pressure;

upstream raw materials:

iodine trichloride

triphenylbismuthane

triphenylbismuth dihydroxide

chlorine

Downstream raw materials:

triphenylbismuthane

3,5-dimethoxyphenyl phenyl ether

3,5-dimethoxy 2-phenylphenol

3,5-dimethoxy 2,6-diphenylphenol

Refernces

• 1、 Kuribara, Takahito,Matsumoto, Koki,Muranaka, Atsuya,Nagasawa, Sho,Nakajima, Masaya,Nemoto, Tetsuhiro,Uchiyama, Masanobu. "A Direct S0→Tn Transition in the Photoreaction of Heavy-Atom-Containing Molecules". supporting information. p. 6847 - 6852. Retrieved 2020/03/23.
• 2、 Solyntjes, Sven,Neumann, Beate,Stammler, Hans-Georg,Ignat'ev, Nikolai,Hoge, Berthold. "Bismuth Perfluoroalkylphosphinates: New Catalysts for Application in Organic Syntheses". . p. 1568 - 1575. Retrieved 2017/02/10.