L-SORBITOL

Base Information

• Chemical Name: L-SORBITOL
• CAS No.: 6706-59-8
• Molecular Formula: C6H14O6
• Molecular Weight: 182.174
• Hs Code.: 29054400
• UNII: 01Q0586BG1
• DSSTox Substance ID: DTXSID4042096
• Nikkaji Number: J441.077G
• Wikidata: Q27103899
• Metabolomics Workbench ID: 51852
• ChEMBL ID: CHEMBL3188639
• Mol file: 6706-59-8.mol

Synonyms:Glucitol,L- (8CI);D-Gulitol;L-Sorbitol;

Chemical Property of L-SORBITOL

Chemical Property:

• Vapor Pressure: 7.22E-12mmHg at 25°C
• Melting Point: 166-168oC
• Refractive Index: 1.597
• Boiling Point: 494.9 °C at 760 mmHg
• PKA: 13.14±0.20(Predicted)
• Flash Point: 292.5 °C
• PSA: 121.38000
• Density: 1.596 g/cm³
• LogP: -3.58540
• Water Solubility.: Soluble in water
• XLogP3: -3.1
• Hydrogen Bond Donor Count: 6
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 5
• Exact Mass: 182.07903816
• Heavy Atom Count: 12
• Complexity: 105

Purity/Quality:

98%, ^*data from raw suppliers

L-Sorbitol ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(C(C(C(CO)O)O)O)O)O
• Isomeric SMILES: C([C@H]([C@@H]([C@H]([C@H](CO)O)O)O)O)O
• Uses: L-Glucitol is L-Isomer of D-Glucitol (S677100), a sugar alcohol obtained from the reduction of glucose and is naturally found in various fruits such as apples, pears and peaches.

Technology Process of L-SORBITOL

There total 79 articles about L-SORBITOL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.2%

cellulose (9004-34-6) → propylene glycol (57-55-6,63625-56-9) + ethylene glycol (107-21-1) + isopropyl alcohol (67-63-0,8013-70-5) + sorbitol (50-70-4,69-65-8,87-78-5,133-43-7,488-44-8,488-45-9,608-66-2,643-01-6,643-03-8,5552-13-6,6706-59-8,24557-79-7,25878-23-3,26566-34-7,45007-61-2,60660-56-2,60660-57-3,60660-58-4,132747-27-4)

Guidance literature:

With water; at 220 ℃; for 0.5h; under 52505.3 Torr; Temperature; Pressure;

Reference yield: 33.6%

cellulose (9004-34-6) → propylene glycol (57-55-6,63625-56-9) + isopropyl alcohol (67-63-0,8013-70-5) + sorbitol (50-70-4,69-65-8,87-78-5,133-43-7,488-44-8,488-45-9,608-66-2,643-01-6,643-03-8,5552-13-6,6706-59-8,24557-79-7,25878-23-3,26566-34-7,45007-61-2,60660-56-2,60660-57-3,60660-58-4,132747-27-4)

Guidance literature:

With water; at 220 ℃; for 0.5h; under 45004.5 Torr; Temperature; Pressure;

Reference yield: 15.8%

cellulose (9004-34-6) → propylene glycol (57-55-6,63625-56-9) + sorbitol (50-70-4,69-65-8,87-78-5,133-43-7,488-44-8,488-45-9,608-66-2,643-01-6,643-03-8,5552-13-6,6706-59-8,24557-79-7,25878-23-3,26566-34-7,45007-61-2,60660-56-2,60660-57-3,60660-58-4,132747-27-4)

Guidance literature:

With hydrogen; In water; at 239.84 ℃; for 4h; under 30003 Torr;

DOI:10.1039/c2gc35685f

upstream raw materials:

L-sorbose

L-gulose

(2R,3S,4S,5S)-2,3,4-Tri-O-benzylhexane-1,2,3,4,5,6-hexol

(E)-3-((4R,5S)-5-Benzhydryloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-propenal

Downstream raw materials:

DL-glucitol hexa-acetate

O¹,O³;O²,O⁴;O⁵,O⁶-trimethanediyl-DL-glucitol

2R,3S,4S,5S-hexitol hexaacetate

DL-iditol hexa-acetate

Refernces

• 1、 Tindall, Daniel J.,Mader, Steffen,Kindler, Alois,Rominger, Frank,Hashmi, A. Stephen K.,Schaub, Thomas. "Selective and Scalable Synthesis of Sugar Alcohols by Homogeneous Asymmetric Hydrogenation of Unprotected Ketoses". supporting information. p. 721 - 725. Retrieved 2020/10/19.
• 2、 Liu, Xiaohao,Liu, Xiaodong,Xu, Guangyue,Zhang, Ying,Wang, Chenguang,Lu, Qiang,Ma, Longlong. "Highly efficient catalytic conversion of cellulose into acetol over Ni-Sn supported on nanosilica and the mechanism study". . p. 5647 - 5656. Retrieved 2019/11/05.