1,3,5-Trithia-2,4,6-tristannacyclohexane, 2,2,4,4,6,6-hexamethyl-

Base Information

• Chemical Name: 1,3,5-Trithia-2,4,6-tristannacyclohexane, 2,2,4,4,6,6-hexamethyl-
• CAS No.: 16892-64-1
• Molecular Formula: C6H18 S3 Sn3
• Molecular Weight: 542.537
• Mol file: 16892-64-1.mol

Synonyms:16892-64-1;1,3,5-Trithia-2,4,6-tristannacyclohexane, 2,2,4,4,6,6-hexamethyl-;Hexamethylcyclotristannathiane;2,2,4,4,6,6-hexamethyl-1,3,5,2,4,6-trithiatristanninane

Chemical Property of 1,3,5-Trithia-2,4,6-tristannacyclohexane, 2,2,4,4,6,6-hexamethyl-

Chemical Property:

• Melting Point: 148-149oC
• PSA: 32.09000
• LogP: 1.43500
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 543.76308
• Heavy Atom Count: 12
• Complexity: 139

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Sn]1(S[Sn](S[Sn](S1)(C)C)(C)C)C

Technology Process of 1,3,5-Trithia-2,4,6-tristannacyclohexane, 2,2,4,4,6,6-hexamethyl-

There total 3 articles about 1,3,5-Trithia-2,4,6-tristannacyclohexane, 2,2,4,4,6,6-hexamethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

bis(trimethyltin) sulfide (1070-91-3) → tetramethylstannane (594-27-4) + 2,2,4,4,6,6-hexamethyl-1,3,5,2,4,6-trithiatristanninane (16892-64-1)

Guidance literature:

In neat (no solvent); Irradiation (UV/VIS); Sn-compd. placed in sealed flask, exposed to daylight radiation for 48 h; solid dissolved in cyclohexane, recrystd., washed; identified by m.p., elem. anal., IR and mass spectra;

DOI:10.1039/c39820000114

Reference yield:

CH3OSn(CH3)2S(NSO2C6H4Cl)Sn(CH3)2SSn(CH3)2NHSO2C6H4Cl (206008-10-8) + water (7732-18-5) → 4-Chlorobenzenesulfonamide (98-64-6) + hydroxydimethyltin sulfite (206008-12-0) + hydroxydimethyltin sulfate (206008-11-9) + 2,2,4,4,6,6-hexamethyl-1,3,5,2,4,6-trithiatristanninane (16892-64-1)

Guidance literature:

In diethyl ether; byproducts: CH3OH; treating with moist ether, sepn. of NaCl and S, filtrate evapn. in vacuum; ppt. washing (hot water), Sn-compd. remaining on the filtration paper, N-compd. pptn. on cooling (5°C), residue insoluble in ether were Sn-containing sulfite and Sn-containing sulfate; IR spectroscopy;

Reference yield:

((CH3)3SbS)2(CH3)2SnCl2 → 2,2,4,4,6,6-hexamethyl-1,3,5,2,4,6-trithiatristanninane (16892-64-1) + trimethylantimony dichloride (13059-67-1,22810-79-3,91108-42-8) + Trimethyl-stibin-sulfid (15082-93-6)

Guidance literature:

In chloroform-d1; reversible dissociation in soln.; monitored by (119)Sn, (13)C NMR spectroscopy;

DOI:10.1002/zaac.200300102

upstream raw materials:

CH₃OSn(CH₃)2S(NSO₂C₆H₄Cl)Sn(CH₃)2SSn(CH₃)2NHSO₂C₆H₄Cl

water

bis(trimethyltin) sulfide

Downstream raw materials:

tin

tetramethylstannane

bis(trimethyltin) sulfide

dimethyltin oxide

Refernces

• 1、 Beckmann, Jens,Dakternieks, Dainis,Duthie, Andrew,Foitzik, Richard C.. "Synthesis, molecular structure, and isomerisation in solution of (ME 3SbS)2Me2SnCl2. Concomitant hypercoordination of tin and antimony". . p. 1508 - 1510. Retrieved 2008/10/08.