DIMETHYL-1,1,1-D3 SULFIDE

Base Information

• Chemical Name: DIMETHYL-1,1,1-D3 SULFIDE
• CAS No.: 4752-12-9
• Molecular Formula: C2H3 D3 S
• Molecular Weight: 65.1118
• Mol file: 4752-12-9.mol

Synonyms:(Methylsulfide)-1,1,1-d3 (7CI,8CI); Methyl perdeuteromethyl sulfide; Methyltrideuteriomethyl sulfide; Trideuteromethyl methyl sulfide

Chemical Property of DIMETHYL-1,1,1-D3 SULFIDE

Chemical Property:

• Vapor Pressure: 8.02 psi ( 20 °C)
• Melting Point: -98 °C(lit.)
• Refractive Index: n20/D 1.433(lit.)
• Boiling Point: 38 °C(lit.)
• Flash Point: °C
• PSA: 25.30000
• Density: 0.862g/cm³
• LogP: 0.97920

Purity/Quality:

Dimethyl-1,1,1-d3Sulfide ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,Xn
• Statements: 11-20/21-41
• Safety Statements: 16-26-33-39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: Dimethyl-1,1,1-d3 Sulfide (CAS# 12/9/4752) is a useful isotopically labeled research compound.

Technology Process of DIMETHYL-1,1,1-D3 SULFIDE

There total 2 articles about DIMETHYL-1,1,1-D3 SULFIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dimethylsulfoxide-d6 (2206-27-1) + methyl iodide (74-88-4) → methanol (67-56-1) + Dimethyl ether (115-10-6,157621-61-9) + dimethylsulfoxide-d5 + Methyl(trideuteriomethyl)sulfid (4752-12-9) + trimethylsulphoxonium-d6 iodide (78730-02-6)

Guidance literature:

In 1,4-dioxane; at 21.84 ℃; for 4.32h; Time; Sealed tube;

DOI:10.1080/17415993.2015.1066376

Reference yield:

dimethylsulfoxide-d6 (2206-27-1) + methyl iodide (74-88-4) → methanol (67-56-1) + Dimethyl ether (115-10-6,157621-61-9) + dimethyl ether-d6 (17222-37-6) + dimethylsulfoxide-d5 + Methyl(trideuteriomethyl)sulfid (4752-12-9) + dimethyl sulfide-d6 (926-09-0) + dimethylsulphoxide-d3 (21892-74-0) + <2H9>trimethylsulphoxonium iodide (23726-00-3) + trimethylsulphoxonium-d6 iodide (78730-02-6)

Guidance literature:

In 1,4-dioxane; at 21.84 ℃; Time; Sealed tube;

DOI:10.1080/17415993.2015.1066376

Reference yield: 76.0%

Methyl(trideuteriomethyl)sulfid (4752-12-9) + 4-chloro-aniline (106-47-8) → N-(4-Chlorphenyl)-S-methyl-S-(trideuteriomethyl)sulfimid (75152-81-7)

Guidance literature:

With N-chloro-succinimide;

upstream raw materials:

dimethylsulfoxide-d6

methyl iodide

Downstream raw materials:

N-(4-Chlorphenyl)-S-methyl-S-(trideuteriomethyl)sulfimid

sulphonium

⁽²⁾H₃S⁽¹⁺⁾

Refernces