L-selectride

Base Information

• Chemical Name: L-selectride
• CAS No.: 38721-52-7
• Molecular Formula: C12H28BLi
• Molecular Weight: 190.10
• Hs Code.: 29319090
• Nikkaji Number: J1.885.704I
• Wikipedia: L-selectride
• Wikidata: Q116065
• Mol file: 38721-52-7.mol

Synonyms:K-selectride;L-selectride;N-selectride;selectride

Chemical Property of L-selectride

Chemical Property:

• Appearance/Colour: clear colourless solution
• Flash Point: 1 °F
• PSA: 0.00000
• Density: 0.89 g/mL at 25 °C
• LogP: 4.61380
• Storage Temp.: Flammables area
• Sensitive.: Moisture Sensitive
• Solubility.: Miscible with tetrahydrofuran.
• Water Solubility.: reacts
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 6
• Exact Mass: 190.2444095
• Heavy Atom Count: 14
• Complexity: 104

Purity/Quality:

99% ^*data from raw suppliers

L-SelectrideSolution(1.0?MinTHF) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F, C
• Hazard Codes: F,C
• Statements: 11-14/15-17-34-35-19-40-37
• Safety Statements: 16-26-36/37/39-43-45-7/8-30

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Li+].[BH-](C(C)CC)(C(C)CC)C(C)CC
• Description: Lithium tri-sec-butylborohydride, commercially available as a one molar solution in tetrahydrofuran. It is widely used as a mild and strong reducing agent with high stereoselectivity in organic synthesis.
• Physical properties: clear colourless solution
• Uses: Lithium triisobutylhydroborate is used as a reducing agent. Reagent for: Enantioselective synthesis of a-amino acids via reduction of N-tert-butanesulfinyl ketimine esters. Diastereoselective reduction reactions. Hydride reduction of the Danishefsky pyranones. Asymmetric reductive aldol reaction of enones with a-alkoxy aldehydes. Synthesis of alkanols by carbonylation reactions. L-Selectride Solution is a reducing agent which is used in the preparation of oxygen heterocycles. Used also as a reactant in the synthesis of novel bicicyclo[3.1.0]hexane analags which may prove useful in the treatment of depression.