Stannane, (2-iodobenzoyloxy)tributyl-

Base Information

• Chemical Name: Stannane, (2-iodobenzoyloxy)tributyl-
• CAS No.: 73927-93-2
• Molecular Formula: C19H31 I O2 Sn
• Molecular Weight: 537.068
• DSSTox Substance ID: DTXSID80224560
• Mol file: 73927-93-2.mol

Synonyms:Stannane, (2-iodobenzoyloxy)tributyl-;73927-93-2;Tributyltin o-iodobenzoate;o-Iodobenzoic acid tributylstannyl ester;BRN 3981018;Benzoic acid, o-iodo-, tributylstannyl ester;DTXSID80224560

Chemical Property of Stannane, (2-iodobenzoyloxy)tributyl-

Chemical Property:

• PSA: 40.13000
• LogP: 4.33260
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 12
• Exact Mass: 538.03908
• Heavy Atom Count: 23
• Complexity: 314

Purity/Quality:

99% ^*data from raw suppliers

O-IODOBENZOIC ACID TRIBUTYLSTANNYL ESTER 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): A poison. TWA 0.1 mg(Sn)/m³; STEL 0.2 mg(Sn)/m³ (skin).
• Hazard Codes: A poison. TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin).

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[Sn](CCCC)(CCCC)OC(=O)C1=CC=CC=C1I

Technology Process of Stannane, (2-iodobenzoyloxy)tributyl-

There total 2 articles about Stannane, (2-iodobenzoyloxy)tributyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

2-Iodobenzoic acid (88-67-5) + bis(tri-n-butyltin)oxide (56-35-9) → (C4H9)3SnOOCC6H4I-2 (73927-93-2)

Guidance literature:

In neat (no solvent); byproducts: H2O; 1:2 mole ratio; exothermic reaction;

DOI:10.1021/je60044a054

Reference yield:

→ (C4H9)3SnOOCC6H4I-2 (73927-93-2)

Guidance literature:

Bu3SnOSnBu3, o-Jodobenzoesaeure;

DOI:10.1021/je60044a054

Reference yield: 80.0%

(C4H9)3SnOOCC6H4I-2 (73927-93-2) → salicylic acid (69-72-7,25496-36-0,8052-31-1)

Guidance literature:

With sodium hydrogencarbonate; In water; at 95 ℃; for 24h;

DOI:10.1016/S0040-4020(98)00202-6

upstream raw materials:

2-Iodobenzoic acid

bis(tri-n-butyltin)oxide

Downstream raw materials:

dimethyl homophthalate

methyl 2-(2-oxopropyl)benzoate

salicylic acid