2 3 7 8 12 13 17 18-OCTAETHYL-21H 23H-

Base Information

• Chemical Name: 2 3 7 8 12 13 17 18-OCTAETHYL-21H 23H-
• CAS No.: 17632-18-7
• Molecular Formula: C36H44N4Zn
• Molecular Weight: 598.162
• Mol file: 17632-18-7.mol

Synonyms:Zinc, [2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphinato(2-)-N21,N22,N23,N24]-, (SP-4-1)-;Zinc, [2,3,7,8,12,13,17,18-octaethylporphinato(2-)]- (8CI);21H,23H-Porphine, 2,3,7,8,12,13,17,18-octaethyl-, zinc complex;(Octaethylporphinato)zinc;(Octaethylporphyrin)zinc;(Octaethylporphyrinato)zinc;β-Octaethylporphyrinatozinc;Zinc octaethylporphine;Zinc octaethylporphyrin;

Chemical Property of 2 3 7 8 12 13 17 18-OCTAETHYL-21H 23H-

Chemical Property:

• PSA: 34.58000
• LogP: 6.13170

Purity/Quality:

98%,99%, ^*data from raw suppliers

2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine zinc(II) 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of 2 3 7 8 12 13 17 18-OCTAETHYL-21H 23H-

There total 10 articles about 2 3 7 8 12 13 17 18-OCTAETHYL-21H 23H- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.9%

zinc(II) acetylacetonate (14024-63-6) + 2,3,7,8,12,13,17,18-octaethyl-porphyrin (2683-82-1,106117-28-6,991-75-3) → (2,3,7,8,12,13,17,18-octaethylporphyrinato)zinc(II) (17632-18-7)

Guidance literature:

In dichloromethane; for 1h; Reflux;

DOI:10.1134/S1070363217120556

Reference yield: 90.0%

zinc diacetate (557-34-6) + 2,3,7,8,12,13,17,18-octaethyl-porphyrin (2683-82-1,106117-28-6,991-75-3) → (2,3,7,8,12,13,17,18-octaethylporphyrinato)zinc(II) (17632-18-7)

Guidance literature:

In methanol; chloroform; for 3h; Reflux;

DOI:10.1142/S1088424619501943

Reference yield:

2,3,7,8,12,13,17,18-octaethylporphyrin (106117-28-6,991-75-3) + zinc diacetate (557-34-6) → (2,3,7,8,12,13,17,18-octaethylporphyrinato)zinc(II) (17632-18-7)

Guidance literature:

In acetonitrile; byproducts: CH3COOH; at 298 K; Kinetics;

upstream raw materials:

zinc diacetate

2,3,7,8,12,13,17,18-octaethyl-porphyrin

2,3,7,8,12,13,17,18-octaethylporphyrin

bis(4,4'-diethyl-3,3',5,5'-tetramethyldipyrroylmethenate)zinc(II)

Downstream raw materials:

(1-methylimidazole)-2,3,7,8,12,13,17,18-octaethylporphinatozinc(II)

N-[Ni(II) 2,3,7,8,12,13,17,18-octaethylporphyrin-5-yl]-N'-phenylurea

C₁₄₉H₁₅₆N₁₉Zn₃⁽³⁺⁾

C₁₁₄H₁₁₄N₁₄Zn₂⁽²⁺⁾

Refernces

• 1、 Brückner, Christian,Chaudhri, Nivedita,Li, Ruoshi,Schnable, David,Zeller, Matthias. "Evaluation of Octaethyl-7,17-dioxobacteriochlorin as a Ligand for Transition Metals". . . Retrieved 2020.
• 2、 Guseva, L. Zh.,Pukhovskaya,Semeikin,Golubchikov. "Coordination dimer based on zinc octaethylporphyrin and meso-pyridyl-substituted porphyrin". . p. 138 - 141. Retrieved 2009.
• 3、 Ivanova,Chizhova,Pukhovskaya,Mamardashvili. "Influence of substituents structure and their electronic effects on acid-base and complexing properties of 5,10,15,20-tetranitro-2,3,7,8,12,13,17, 18-octaethylporphyrin". . . Retrieved 2014.
• 4、 Ivanova, Yu. B.,Koifman, O. I.,Kruk, M. M.,Pukhovskaya, S. G.. "Enthalpy—entropy compensation upon metal ion coordination with porphyrins: generalization for the free bases and doubly deprotonated macrocycles". . p. 1072 - 1075. Retrieved 2020/07/25.