1,6-Divinylperfluorohexane

Base Information

• Chemical Name: 1,6-Divinylperfluorohexane
• CAS No.: 1800-91-5
• Molecular Formula: C10H6 F12
• Molecular Weight: 354.138
• Hs Code.: 2903399090
• European Community (EC) Number: 217-288-0
• UNII: 9KC63N97TA
• DSSTox Substance ID: DTXSID20170895
• Nikkaji Number: J199.623A
• Wikidata: Q27272668
• Mol file: 1800-91-5.mol

Synonyms:1,6-Divinylperfluorohexane;1800-91-5;3,3,4,4,5,5,6,6,7,7,8,8-Dodecafluorodeca-1,9-diene;Dodecafluoro-1,9-decadiene;EINECS 217-288-0;UNII-9KC63N97TA;9KC63N97TA;3,3,4,4,5,5,6,6,7,7,8,8-Dodecafluoro-1,9-decadiene;C10H6F12;1,6-Divinyl Perfluorohexane;1,6-divinyl(perfluorohexane);SCHEMBL155212;DTXSID20170895;MFCD00077521;AKOS015836273;C10-H6-F12;BS-21766;CS-0207374;FT-0607011;A812518;J-011501;Q27272668;1,9-Decadiene, 3,3,4,4,5,5,6,6,7,7,8,8-dodecafluoro-

Chemical Property of 1,6-Divinylperfluorohexane

Chemical Property:

• Vapor Pressure: 2.05mmHg at 25°C
• Refractive Index: 1.506
• Boiling Point: 169.4 °C at 760 mmHg
• Flash Point: 57.3 °C
• PSA: 0.00000
• Density: 1.419 g/cm³
• LogP: 5.17020
• Water Solubility.: 1.61mg/L at 20℃
• XLogP3: 5.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 12
• Rotatable Bond Count: 7
• Exact Mass: 354.0277881
• Heavy Atom Count: 22
• Complexity: 405

Purity/Quality:

99.9% ^*data from raw suppliers

1,6-Divinylperfluorohexane 99% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F
• Hazard Codes: F
• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CC(C(C(C(C(C(C=C)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F

Technology Process of 1,6-Divinylperfluorohexane

There total 4 articles about 1,6-Divinylperfluorohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

1,10-diiodo-3,3,4,4,5,5,6,6,7,7,8,8-dodecafluorodecane (1813-83-8) → 3,3,4,4,5,5,6,6,7,7,8,8-dodecafluoro-1,9-decadiene (1800-91-5)

Guidance literature:

With potassium hydroxide; In ethylene glycol; at 140 ℃;

DOI:10.1021/jo00133a003

Reference yield:

→ 3,3,4,4,5,5,6,6,7,7,8,8-dodecafluoro-1,9-decadiene (1800-91-5)

Guidance literature:

3,3,4,4,5,5,6,6,7,7,8,8-Dodecafluor-1,10-diiod-decan, ethanol. KOH, erwaermen;

Reference yield:

dodecafluoro-1,6-diiodohexane (375-80-4) → 3,3,4,4,5,5,6,6,7,7,8,8-dodecafluoro-1,9-decadiene (1800-91-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 75 percent / CuI / acetonitrile / 15 h / 165 °C

2: 75 percent / KOH / ethanol / 5 h / 70 °C

With potassium hydroxide; copper(l) iodide; In ethanol; acetonitrile;

DOI:10.1016/0022-1139(95)03231-2

upstream raw materials:

1,10-diiodo-3,3,4,4,5,5,6,6,7,7,8,8-dodecafluorodecane

dodecafluoro-1,6-diiodohexane

Downstream raw materials:

α,ω-di(trichlorosilyl)-1H,1H,2H,2H,9H,9H,10H,10H-perfluorodecane

Refernces

• 1、 Manseri, A.,Ameduri, B.,Boutevin, B.,Kotora, M.,Hajek, M.,Caporiccio, G.. "Synthesis of telechelic dienes from fluorinated α,ω-diiodoalkanes. Part I. Divinyl and diallyl derivatives from model I(C2F4)nI compounds". . p. 151 - 158. Retrieved 2007/10/02.