Triazamate

Base Information

• Chemical Name: Triazamate
• CAS No.: 112143-82-5
• Deprecated CAS: 110895-43-7
• Molecular Formula: C₁₃H₂₂N₄O₃S
• Molecular Weight: 314.409
• European Community (EC) Number: 411-650-3
• UNII: B4914SW93T
• DSSTox Substance ID: DTXSID5034307
• Nikkaji Number: J679.699K
• Wikidata: Q3538727
• Metabolomics Workbench ID: 55914
• Mol file: 112143-82-5.mol

Synonyms:triazamate

Chemical Property of Triazamate

Chemical Property:

• Vapor Pressure: 1.6 x l0-4 Pa (25 °C)
• Melting Point: 60°
• Refractive Index: 1.6200 (estimate)
• Boiling Point: 280°C (rough estimate)
• PKA: 0.48±0.50(Predicted)
• Flash Point: 189℃
• PSA: 102.62000
• Density: 1.2357 (rough estimate)
• LogP: 1.76050
• Water Solubility.: 433 mg l-1(25 °C)
• XLogP3: 2.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 6
• Exact Mass: 314.14126175
• Heavy Atom Count: 21
• Complexity: 384

Purity/Quality:

98%,99%, ^*data from raw suppliers

Triazamate analytical standard ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T,N
• Hazard Codes: T,N
• Statements: 23-25-36-50
• Safety Statements: 26-45-61

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCOC(=O)CSC1=NC(=NN1C(=O)N(C)C)C(C)(C)C
• Uses: Pesticide. Triazamate is used for the control of aphids by foliar application on a wide variety of crops. It is suitable for inclusion in integrated pest management because it is minimally toxic to beneficial insects. Triazamate is used in controlling unpleasant pests.Used in preparation of Thiazole Manganese Zinc compounds and compounds thereof.

Technology Process of Triazamate

There total 2 articles about Triazamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-t-butyl-5-carboethoxymethylthio-1H-1,2,4-triazole (110895-85-7) + diethyl ether (60-29-7,927820-24-4) + N,N-Dimethylcarbamoyl chloride (79-44-7) → triazamate (112143-82-5,110895-43-7)

Guidance literature:

With dmap; triethylamine; In tetrahydrofuran; water;

Reference yield:

3-t-butyl-5-carboethoxymethylthio-1H-1,2,4-triazole (110895-85-7) + N,N-Dimethylcarbamoyl chloride (79-44-7) → triazamate (112143-82-5,110895-43-7)

Guidance literature:

With pyridine; dmap;

upstream raw materials:

3-t-butyl-5-carboethoxymethylthio-1H-1,2,4-triazole

N,N-Dimethylcarbamoyl chloride

diethyl ether

Refernces

• 1、 -. "1-dimethylcarbamoyl-3-t-butyl-5-substituted-1H-1,2,4-triazoles". . . Retrieved 2008/06/13.