p-Anisaldehyde ethylene acetal

Base Information

• Chemical Name: p-Anisaldehyde ethylene acetal
• CAS No.: 2403-50-1
• Molecular Formula: C10H12 O3
• Molecular Weight: 180.203
• Hs Code.: 2932999099
• Mol file: 2403-50-1.mol

Synonyms:1,3-Dioxolane,2-(p-methoxyphenyl)- (7CI,8CI); 2-(4-Methoxyphenyl)-1,3-dioxolane;2-(p-Methoxyphenyl)-1,3-dioxolane; 2-p-Anisyl-1,3-dioxolane;4-Methoxybenzaldehyde ethylene acetal; 4-Methoxybenzaldehyde ethylene glycolacetal; Anisic aldehyde ethylene glycol acetal; NSC 6555; p-Anisaldehyde cyclicethylene acetal

Chemical Property of p-Anisaldehyde ethylene acetal

Chemical Property:

• Vapor Pressure: 0.00619mmHg at 25°C
• Boiling Point: 281.1°C at 760 mmHg
• Flash Point: 93.1°C
• PSA: 27.69000
• Density: 1.133g/cm³
• LogP: 1.74060

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of p-Anisaldehyde ethylene acetal

There total 9 articles about p-Anisaldehyde ethylene acetal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

4-methoxy-benzaldehyde (123-11-5) + ethylene glycol (107-21-1) → 2-(4-methoxyphenyl)-1,3-dioxolane (2403-50-1)

Guidance literature:

With polyaniline-sulfate salt; In toluene; for 0.75h; Heating;

DOI:10.1055/s-2003-41412

Reference yield: 92.0%

C17H17IO5 → 2-(4-methoxyphenyl)-1,3-dioxolane (2403-50-1)

Guidance literature:

With pyridine; fac-tris(2-phenylpyridinato-N,C₂')iridium(III); In acetonitrile; at 30 ℃; for 3h; Inert atmosphere; Irradiation;

DOI:10.1021/acs.orglett.0c03058

Reference yield: 92.0%

4-methoxy-benzaldehyde (123-11-5) + orthoformic acid triethyl ester (122-51-0) → 2-(4-methoxyphenyl)-1,3-dioxolane (2403-50-1)

Guidance literature:

With tetrabutylammomium bromide; at 20 ℃; for 9h; Inert atmosphere;

DOI:10.1021/acs.joc.8b02965

upstream raw materials:

4-methoxy-benzaldehyde

ethylene glycol

2-<2-(2-methoxyethoxy)ethoxy>-1,3-dioxolan

4-methoxyphenyl magnesium bromide

Downstream raw materials:

2-(2,2,2-trifluoro-1-(4-methoxyphenyl)ethyl)-1,3-dioxolane

8-(4-methoxyphenyl)quinoline

ethyl (2E)-2-cyano-3-(4-methoxyphenyl)acrylate

4-methoxy-benzaldehyde

Refernces

• 1、 Salmoria,Neves,Dall'Oglio,Zucco. "Preparation of aromatic ethers and dioxolanes under microwave irradiation". . p. 3323 - 3328. Retrieved 2001.
• 2、 Andersson, Claes-Henrik,Berggren, Gustav,Ott, Sascha,Grennberg, Helena. "Synthesis and IR spectroelectrochemical studies of a [60] fulleropyrrolidine-(tricarbonyl)chromium complex: Probing C60 redox states by IR spectroscopy". . p. 1744 - 1749. Retrieved 2011.
• 3、 Han, Bingbing,Hu, Junjun,Li, Xianwei,Zheng, Zubiao. "Application of poly(Vinylbenzyltrimethylammonium tribromide) resin as an efficient polymeric catalyst in the acetalization and diacetylation of benzaldehydes". supporting information. p. 287 - 293. Retrieved 2021/04/28.