9-OXO-NONANOIC ACID METHYL ESTER

Base Information

• Chemical Name: 9-OXO-NONANOIC ACID METHYL ESTER
• CAS No.: 1931-63-1
• Molecular Formula: C10H18O3
• Molecular Weight: 186.251
• Hs Code.: 2918300090
• Mol file: 1931-63-1.mol

Synonyms:Azelaaldehydicacid, methyl ester (6CI,7CI,8CI);Caprylic acid, h-formyl-, methyl ester (4CI);8-Formyloctanoic acidmethyl ester;9-Methoxy-9-oxononanal;9-Oxononanoic acid methyl ester;Azelaicacid aldehyde methyl ester;Methyl 8-formyloctanoate;Methyl 9-oxononanoate;Methyl azelaaldehydate;NSC 53771;

Chemical Property of 9-OXO-NONANOIC ACID METHYL ESTER

Chemical Property:

• Vapor Pressure: 0.023mmHg at 25°C
• Refractive Index: 1.431
• Boiling Point: 249.4°Cat760mmHg
• Flash Point: 101.8°C
• PSA: 43.37000
• Density: 0.958g/cm³
• LogP: 2.08900
• Storage Temp.: Hygroscopic, -20°C Freezer, Under inert atmosphere
• Solubility.: Chloroform (Slightly), DMSO (Slightly), Ethyl Acetate (Slightly)

Purity/Quality:

99%, ^*data from raw suppliers

Methyl 9-Oxononanoate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Methyl 9-Oxononanoate is a linseed oil-based coating. It is solventless polymeric protective.

Technology Process of 9-OXO-NONANOIC ACID METHYL ESTER

There total 91 articles about 9-OXO-NONANOIC ACID METHYL ESTER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Methyl oleate (112-62-9) → caprinaldehyde (112-31-2) + Octanoic acid (124-07-2) + methyl octanate (111-11-5) + nonanoic acid (112-05-0) + 1-decanoic acid (334-48-5) + 2-decenal (2497-25-8,3913-81-3,3913-71-1) + methyl ester of azelaic acid aldehyde (1931-63-1) + (2E)-undecenal (53448-07-0) + methyl 10-oxodec-8-enoate (65114-83-2) + methyl 11-oxo-9-undecenoate

Guidance literature:

In glycerol; at 180 ℃; for 15h;

DOI:10.1016/j.chemphyslip.2012.02.004

Reference yield:

methyl colnelenate (52077-22-2) → 2E,6Z-nonadienal (557-48-2,26370-28-5) + methyl ester of azelaic acid aldehyde (1931-63-1)

Guidance literature:

With hydrogenchloride; In methanol; for 18h; Ambient temperature;

DOI:10.1039/P19910000567

Reference yield:

methyl (Z)-9,10-epoxy-13-oxo-(E)-11-octadecenoate + methyl (Z)-12,13-epoxy-9-oxo-(E)-10-octadecenoate → 2-pentylfuran (3777-69-3) + 8-(2-Furyl)octansaeure-methylester (38199-50-7) + methyl 9-(5-pentylfuryl-2-)-8-nonenoate (68532-61-6) + methyl ester of azelaic acid aldehyde (1931-63-1) + methyl 8-<5-(1'-hexenyl)furyl-2->-octanoate + methyl 9-hydroxy-9-(5-pentylfuryl-2-)-nonanoate

Guidance literature:

With Amberlite resin IRA-400 (OH^-); In methanol; at 37 ℃; Mechanism; also with glycine methyl ester;

DOI:10.1016/0009-3084(95)02449-S

upstream raw materials:

9-cis,11-trans,13-cis-octadecatrienoic acid

Methyl oleate

methyl 9-chloro-9-oxononanoate

methyl 9,10-dihydroxy stearate

Downstream raw materials:

methyl tridec-9-enoate

(Z)-9-hexadecenoic acid methyl ester

18-Hydroxyoleic acid

α-Elaeostearinsaeuremethylester

Refernces

• 1、 Wang, Huijing,Chang, Tina,Konduri, Srihari,Huang, Jianbo,Saghatelian, Alan,Siegel, Dionicio. "Synthesis of chemically edited derivatives of the endogenous regulator of inflammation 9-PAHSA". . p. 498 - 506. Retrieved 2019.
• 2、 Perlikowska, Wieslawa,Mikolajczyk, Marian. "A concise approach to both enantiomers of phytoprostane B1 type II". . p. 1767 - 1771. Retrieved 2011.
• 3、 Delbeke,Roman,Marin,Van Geem,Stevens. "A new class of antimicrobial biosurfactants: Quaternary ammonium sophorolipids". . p. 3373 - 3377. Retrieved 2015.
• 4、 Gorczynski, Michael J.,Huang, Jinming,King, S. Bruce. "Regio- and stereospecific syntheses and nitric oxide donor properties of (E)-9- and (E)-10-nitrooctadec-9-enoic acids". . p. 2305 - 2308. Retrieved 2006.
• 5、 Huang, Zuoxin,Lin, Min,Peng, Xinxin,Shu, Xingtian,Xia, Changjiu,Xin, Shihao,Zhang, Yao,Zheng, Aiguo,Zhu, Bin. "Spongy titanosilicate promotes the catalytic performance and reusability of WO3 in oxidative cleavage of methyl oleate". . p. 5135 - 5144. Retrieved 2022/02/25.
• 6、 Xiao, Hong-Xiu,Yan, Qing-Xiang,He, Zhi-Hui,Zou, Zheng-Biao,Le, Qing-Qing,Chen, Ting-Ting,Cai, Bing,Yang, Xian-Wen,Luo, Su-Lan. "Total synthesis and anti-inflammatory bioactivity of (?)-majusculoic acid and its derivatives". . . Retrieved 2021/06/11.