Diphenyl(methoxy)methane

Base Information

• Chemical Name: Diphenyl(methoxy)methane
• CAS No.: 1016-09-7
• Molecular Formula: C14H14 O
• Molecular Weight: 198.265
• Mol file: 1016-09-7.mol

Synonyms:Ether,diphenylmethyl methyl (6CI,7CI,8CI); Benzhydrol methyl ether; Benzhydryl methylether; Diphenylmethyl methyl ether; Methoxydiphenylmethane; NSC 75

Chemical Property of Diphenyl(methoxy)methane

Chemical Property:

• Boiling Point: 270.6°Cat760mmHg
• Flash Point: 122.6°C
• PSA: 9.23000
• Density: 1.03g/cm³
• LogP: 3.42240

Purity/Quality:

98%,99%, ^*data from raw suppliers

DIPHENYLMETHYL METHYL ETHER Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Diphenyl(methoxy)methane

There total 150 articles about Diphenyl(methoxy)methane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

methanol (67-56-1) + Benzhydrylidene-((2S,3S)-2,3-diphenyl-aziridin-1-yl)-amine → stilbene (588-59-0) + benzhydryl methyl ether (1016-09-7)

Guidance literature:

Mechanism; Rate constant; Irradiation;

DOI:10.1016/0040-4039(95)02416-6

Reference yield: 22.0%

1,1,1-triphenylbut-2-ene (2650-86-4) → biphenyl (92-52-4,1594-86-1) + 1-phenylpropene (637-50-3) + benzhydryl methyl ether (1016-09-7) + 1-methoxy-1-phenylbut-2-ene (57767-02-9) + 2-methyl-1,1,3-triphenylcyclopropane (130138-97-5)

Guidance literature:

In methanol; for 2h; Quantum yield; Product distribution; Irradiation; irradiation in benzene solution;

DOI:10.1246/cl.1990.1079

Reference yield: 8.0%

3,3,3-triphenyl-propene (3282-07-3) → styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + biphenyl (92-52-4,1594-86-1) + (1,2-diphenylcyclopropyl)benzene (896-65-1) + benzhydryl methyl ether (1016-09-7) + 1-phenylallyl methyl ether (22665-13-0)

Guidance literature:

In methanol; for 2h; Quantum yield; Product distribution; Irradiation;

DOI:10.1246/cl.1990.1079

upstream raw materials:

methanol

1,1-Diphenylmethanol

2,2-diphenylacetic acid

benzhydryl-trimethyl-ammonium; bromide

Downstream raw materials:

tetraphenylethane-1,2-diol

1,2-dimethoxy-1,1,2,2-tetraphenyl-ethane

1-(2-fluoro-phenyl)-2,2-diphenyl-ethanone

3,3-diphenylpropan-1-ol

Refernces

• 1、 Closs,Rabinow. "-". . p. 8190. Retrieved 1976.
• 2、 Namboodiri, Vasudevan V,Varma, Rajender S. "Iron-catalyzed solvent-free conversion of alcohols and phenols into diphenylmethyl (DPM) ethers". . p. 4593 - 4595. Retrieved 2002.
• 3、 Zayas, Jose,Platz, Matthew S.. "THE EFFECT OF OXYGEN ON THE MATRIX CHEMISTRY OF DIPHENYLCARBENE". . p. 2853 - 2856. Retrieved 1985.
• 4、 Eisenthal, K.B.,Turro, N.J.,Aikawa, M.,Butcher, J.A.,DuPuy, C.,et al.. "Dynamics and Energetics of the Singlet-Triplet Interconversion of Diphenylcarbene". . p. 6563 - 6565. Retrieved 1980.
• 5、 Krogh, Erik,Wan, Peter. "GENERAL METHOD FOR THE PHOTOGENERATION OF BENZOLATED CATIONIC AND ANIONIC SYSTEMS IN AQUEOUS SOLUTION. TEST OF RELATIVE STABILITY OF THESE SYSTEMS IN THE EXCITED STATE.". . p. 823 - 826. Retrieved 1986.
• 6、 Alt, R.,Gould, I. R.,Staab, H. A.,Turro, N. J.. "Structural Control of the Triplet-Singlet Equilibrium in Cyclophane Diarylcarbenes". . p. 6911 - 6914. Retrieved 1986.
• 7、 Petrellis,Griffin. "". . p. 691. Retrieved 1967.
• 8、 Yamaguchi,Kuriyama,Sakuragi,Tokumaru. "Electron transfer between neutral radicals generated from photolysis of diphenylmethyl 1-naphthalenecarboxylate in polar solvents". . p. 5529 - 5532. Retrieved 1992.
• 9、 Leyva, Elisa,Barcus, Robert L.,Platz, Matthew S.. "Reinvestigation of the Chemistry of Arylcarbenes in Polycrystalline Alcohols at 77 K. Secondary Photochemistry of Matrix-Isolated Carbenes". . p. 7786 - 7788. Retrieved 1986.
• 10、 Tabaei, Seyed-Mohammad H.,Satarinezhad, Elaheh,Seradj, Seyed-Hassan,Ebrahimian, Gholam-Reza. "The first complete dechlorination of 1,1,1-trichloro-2,2-bis(4- chlorophenyl) ethane (P,P'-DDT) using metal-promoted alkoxyborohydride in a protic solvent". . p. 43 - 51. Retrieved 2000.