1,3-Diphenylpropene

Base Information

• Chemical Name: 1,3-Diphenylpropene
• CAS No.: 5209-18-7
• Molecular Formula: C15H14
• Molecular Weight: 194.276
• NSC Number: 167100
• Nikkaji Number: J374.752B,J343.870H
• Mol file: 5209-18-7.mol

Synonyms:1,3-diphenylpropene

Chemical Property of 1,3-Diphenylpropene

Chemical Property:

• XLogP3: 4.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 194.109550447
• Heavy Atom Count: 15
• Complexity: 180

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)CC=CC2=CC=CC=C2
• Isomeric SMILES: C1=CC=C(C=C1)C/C=C/C2=CC=CC=C2

Technology Process of 1,3-Diphenylpropene

There total 250 articles about 1,3-Diphenylpropene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

4-Methylbenzyl alcohol (589-18-4) + 1,3-diphenylallyl chloride (42759-96-6) → 1,3-diphenylpropene (3412-44-0,1138-83-6,5209-18-7) + 4-methyl-benzaldehyde (104-87-0)

Guidance literature:

With iron(III) chloride hexahydrate; In toluene; at 80 ℃;

DOI:10.1007/s11426-013-5042-2

Reference yield: 91.0%

(3-benzyloxy-3-phenylprop-1-enyl)benzene → 1,3-diphenylpropene (3412-44-0,1138-83-6,5209-18-7) + benzaldehyde (100-52-7)

Guidance literature:

With iron(III) chloride hexahydrate; In toluene; at 80 ℃; for 0.5h;

DOI:10.1007/s11426-013-5042-2

Reference yield: 90.0%

1,3-diphenylallyl chloride (42759-96-6) + benzyl alcohol (100-51-6,185532-71-2) → 1,3-diphenylpropene (3412-44-0,1138-83-6,5209-18-7) + benzaldehyde (100-52-7)

Guidance literature:

With iron(III) chloride hexahydrate; In toluene; at 80 ℃;

DOI:10.1007/s11426-013-5042-2

upstream raw materials:

1,3-diphenylpropan-1-ol

(E)-3-Ureido-but-2-enoic acid ethyl ester

2,3-diphenyl-1-propanol

potassium benzyloxide

Downstream raw materials:

2-benzyl-3-phenyloxirane

1,2-dibromo-1,3-diphenyl-propane

1,3-diphenylpropane

1,1'-(1,3-propanediyl)biscyclohexane

Refernces

• 1、 -. "Method for preparing alkane through coupling of primary alcohol catalyzed by N-heterocyclic carbene metal compound". Paragraph 0079-0100. . Retrieved 2021/08/19.
• 2、 Zhang, Guo-Min,Zhang, Hua,Wang, Bei,Wang, Ji-Yu. "Boron-catalyzed dehydrative allylation of 1,3-diketones and β-ketone esters with 1,3-diarylallyl alcohols in water". . p. 17025 - 17031. Retrieved 2021/05/25.