(Z)-4-Oxo-7-decenal

Base Information

• Chemical Name: (Z)-4-Oxo-7-decenal
• CAS No.: 41031-87-2
• Molecular Formula: C10H16 O2
• Molecular Weight: 168.236
• Hs Code.: 2914400090
• European Community (EC) Number: 255-181-0
• DSSTox Substance ID: DTXSID001313759
• Nikkaji Number: J294.812E
• Mol file: 41031-87-2.mol

Synonyms:(Z)-4-Oxo-7-decenal;41031-87-2;EINECS 255-181-0;(z)-4-oxodec-7-en-1-al;7-Decenal, 4-oxo-, (Z)-;DTXSID001313759

Chemical Property of (Z)-4-Oxo-7-decenal

Chemical Property:

• Vapor Pressure: 0.0089mmHg at 25°C
• Boiling Point: 265.9°C at 760 mmHg
• Flash Point: 98.4°C
• PSA: 34.14000
• Density: 0.926g/cm³
• LogP: 2.28100
• XLogP3: 1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 7
• Exact Mass: 168.115029749
• Heavy Atom Count: 12
• Complexity: 159

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC=CCCC(=O)CCC=O
• Isomeric SMILES: CC/C=C\CCC(=O)CCC=O

Technology Process of (Z)-4-Oxo-7-decenal

There total 36 articles about (Z)-4-Oxo-7-decenal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

(Z)-4,4-diethoxydec-7-enal → (Z)-4-oxodec-7-enal (41031-87-2)

Guidance literature:

With hydrogenchloride; water; In tert-butyl methyl ether;

DOI:10.2533/chimia.2019.194

Reference yield: 91.0%

(Z)-3-bromo-1,1-diethoxy-7-decen-4-one → (Z)-4-oxodec-7-enal (41031-87-2)

Guidance literature:

With chromium chloride; lithium aluminium tetrahydride;

DOI:10.1246/bcsj.57.1935

Reference yield: 87.0%

(Z)-dec-7-ene-1,4-diol → (Z)-4-oxodec-7-enal (41031-87-2)

Guidance literature:

(Z)-dec-7-ene-1,4-diol; With oxalyl dichloride; dimethyl sulfoxide; In dichloromethane; at -40 - -10 ℃; for 0.25h;

With triethylamine; In dichloromethane; at -10 ℃; for 0.0833333h;

DOI:10.2533/chimia.2019.194

upstream raw materials:

(Z)-1-bromo-2-pentene

2-ethoxy-3-vinylsulfanyl-propene

1-nitro-dec-7c-en-4-one

1-[1,3]dioxolan-2-yl-non-6c-en-3-one

Downstream raw materials:

methyl jasmonate

(Z)-2-(2-(but-2-en-1-yl)-3-oxocyclopentyl)acetic acid

methyl jasmonate

(Z)-2-(2-pentenyl)-2-cyclopenten-1-one

Refernces

• 1、 Dubs,Stussi. "Synthesis of three jasmin constituents via a central intermediate". . p. 990 - 997. Retrieved 1978.
• 2、 Geraghty, Niall W. A.,Morris, Noreen M.. "Synthesis of 2-Alkyl-2-cyclopenten-1-ones. A Versatile Kinetic Alkylation-Ozonolysis Procedure for the Preparation of γ-Ketoaldehydes". . p. 603 - 607. Retrieved 2007/10/02.
• 3、 Morizawa, Yoshitomi,Kanakura, Akihiro,Yamamoto, Hajime,Hiyama, Tamejiro,Nozaki, Hitosi. "1-Bromo-2-ethoxycyclolithium: A Synthetic Equivalent of 2-Lithio or 3-Lithiopropenal. Application to the Synthesis of Juvenile Hormone (JH-II), β-Sinensal, and Jasmonoids.". . p. 1935 - 1942. Retrieved 2007/10/02.