beta-D-Glucopyranoside, methyl 2-[(acetyloxy)mercurio]-2-deoxy-, triacetate

Base Information

• Chemical Name: beta-D-Glucopyranoside, methyl 2-[(acetyloxy)mercurio]-2-deoxy-, triacetate
• CAS No.: 35822-13-0
• Molecular Formula: C15H23HgO10
• Molecular Weight: 563.9271
• DSSTox Substance ID: DTXSID70586785
• NSC Number: 321242,157060
• Mol file: 35822-13-0.mol

Synonyms:35822-13-0;DTXSID70586785;MSZGNJCTNAZSPR-UHFFFAOYSA-M;NSC157060;NSC321242;NSC-157060;NSC-321242;Methyl ethane-3,4,6-tri-O-acetyl-2-deoxy-2-mercuryylhexopyranoside;.beta.-D-Glucopyranoside, methyl 2-[(acetyloxy)mercurio]-2-deoxy-, triacetate

Chemical Property of beta-D-Glucopyranoside, methyl 2-[(acetyloxy)mercurio]-2-deoxy-, triacetate

Chemical Property:

• PSA: 123.66000
• LogP: 0.13330
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 10
• Rotatable Bond Count: 10
• Exact Mass: 564.091940
• Heavy Atom Count: 26
• Complexity: 537

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=O)OCC1C(C(C(C(O1)OC)[Hg]OC(=O)C)OC(=O)C)OC(=O)C

Technology Process of beta-D-Glucopyranoside, methyl 2-[(acetyloxy)mercurio]-2-deoxy-, triacetate

There total 3 articles about beta-D-Glucopyranoside, methyl 2-[(acetyloxy)mercurio]-2-deoxy-, triacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methanol (67-56-1) + mercury(II) diacetate (1600-27-7) + D-glucal triacetate (2873-29-2) → C15H22HgO10 (35822-13-0) + C15H22HgO10 (35822-14-1)

Guidance literature:

In methanol; at 23 ℃; for 2.5h; Yield given. Yields of byproduct given;

DOI:10.1021/ja00524a046

Reference yield:

→ D-Glucal-3.4.6-triacetat-acetoxyquecksilber-methoxid (35822-13-0,35822-14-1,35822-15-2)

Guidance literature:

D-Glucal-3.4.6-triacetat, Hg-Acetat/Methanol (1 h, Raumtemp.);

DOI:10.1021/ja00870a036

Reference yield:

→ Methyl-3,4,6-tri-O-acetyl-2-acetoxymercuri-2-deoxy-β-D-glucopyranosid (35822-13-0)

Guidance literature:

3,4,6-Tri-O-acetyl-D-glucal, Oxymercurierung - Deoxymercurierung mit und ohne Jodid als Kat.;

DOI:10.1016/S0040-4039(01)85189-3

upstream raw materials:

methanol

mercury(II) diacetate

D-glucal triacetate

Refernces

• 1、 DeBoer, Andrew,Thanel, Christopher J.,Wilson, Greg A.. "A convenient preparation of methyl 4,6-Di-O-acetyl-2,3-dideoxy-β-D-erythro-hex-2-enopyranoside". . p. 5137 - 5138. Retrieved 2007/10/12.