Silver hexafluoroantimonate

Base Information

• Chemical Name: Silver hexafluoroantimonate
• CAS No.: 26042-64-8
• Molecular Formula: Ag*F₆Sb
• Molecular Weight: 343.609
• Hs Code.: 28432900
• Wikidata: Q36426856
• Mol file: 26042-64-8.mol

Synonyms:Silver hexafluoroantimonate;26042-64-8;Silver hexafluoroantimonate(V);Silverhexafluoroantimonate;silver;hexafluoroantimony(1-);silver hexafluorostiboranuide;AgSbF6;silver hexafluorostibate(V);silver (I)hexafluoroantimonate;silver(I) hexafluorostibate(V);Silver(I) hexafluoroantimonate(V);MFCD00003401;Silver hexafluoroantimonate(V), 98%;AKOS015904205;silver hexakis(fluoranyl)antimony(1-);DB-231767;NS00084211;S0463;D78354;A818149;Q36426856

Chemical Property of Silver hexafluoroantimonate

Chemical Property:

• Appearance/Colour: White to pale yellow crystalline powder
• PSA: 0.00000
• LogP: 2.52120
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Sensitive.: Hygroscopic
• Water Solubility.: Soluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 0
• Exact Mass: 341.79932
• Heavy Atom Count: 8
• Complexity: 62.7

Purity/Quality:

99.9% ^*data from raw suppliers

Silver Hexafluoroantimonate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn,N,C
• Hazard Codes: Xn,N,C
• Statements: 20/22-51/53
• Safety Statements: 61

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: F[Sb-](F)(F)(F)(F)F.[Ag+]
• Uses: Silver Hexafluoroantimonate(V) is used as a catalyst in the synthesis of isocoumarins through benzothiadiazine-fused.

Technology Process of Silver hexafluoroantimonate

There total 17 articles about Silver hexafluoroantimonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

antimony pentafluoride (7783-70-2) + silver fluoride (11113-87-4) → silver hexafluoroantimonate (26042-64-8)

Guidance literature:

In hydrogen fluoride; HF (liquid); cooling with solid CO2 and acetone; some min. shaking; warming to 0°C;; precipitation dried in vacuum;;

Reference yield:

silver(I) chlorate (7783-92-8) + nitronium hexafluoroantimonate (17856-92-7) + water (7732-18-5) → silver hexafluoroantimonate (26042-64-8) + nitryl chlorate + nitric acid (7697-37-2,78989-43-2) + silver perchlorate + dinitrogen monoxide (10024-97-2)

Guidance literature:

In nitromethane; room temp., traces of H2O in nitromethane; N2O was detected by MS, HNO3 was detected by (14)N NMR;

DOI:10.1002/zaac.200500518

Reference yield:

silver tetrafluoroborate (14104-20-2) + Br2F(1+)*SbF6(1-)=Br2FSbF6 → silver hexafluoroantimonate (26042-64-8) + bromine trifluoride (7787-71-5)

Guidance literature:

DOI:10.1039/JR9490002865

upstream raw materials:

silver(I) chlorate

nitronium hexafluoroantimonate

water

hydrogen fluoride

Downstream raw materials:

trans-bis{diphenyl(2-tetrahydrofuranylmethyl)phosphane-O',P'}palladium(II) bis{hexafluoroantimonate(V)

diphenylphosphino 3-methylbut-2-enoate bis(triphenylphosphine)rhodium(I) hexafluoroantimonate

{Rh(1,5-cyclooctadiene)(η2-(o-bromophenyl)diphenylphosphine)}SbF6

[Rh(cyclo-octa-1,5-diene)2][SbF₆]

Refernces

• 1、 Mazej, Zoran,Micha?owski, Tomasz,Goreshnik, Evgeny A.,Jagli?i?, Zvonko,Ar?on, Iztok,Szyd?owska, Jadwiga,Grochala, Wojciech. "The first example of a mixed valence ternary compound of silver with random distribution of Ag(i) and Ag(ii) cations". . p. 10957 - 10968. Retrieved 2015.
• 2、 Caballero, Agustín,Guerrero, Ana,Jalón, Félix A.,Manzano, Blanca R.,Claramunt, Rosa M.,Santa María, M. Dolores,Escolástico, Consuelo,Elguero, José. "Multinuclear NMR solution studies on complexes of hexakis(pyrazol-1-yl)benzene (hpzb) with Ag(I)". . p. 168 - 174. Retrieved 2008/10/08.