Hexyl glycidyl ether

Base Information

• Chemical Name: Hexyl glycidyl ether
• CAS No.: 5926-90-9
• Molecular Formula: C9H18 O2
• Molecular Weight: 158.241
• European Community (EC) Number: 227-662-5
• NSC Number: 83416
• UNII: 0V30H1KF4J
• DSSTox Substance ID: DTXSID9025405
• Nikkaji Number: J223.891H
• Wikidata: Q27237284
• Mol file: 5926-90-9.mol

Synonyms:HEXYL GLYCIDYL ETHER;Glycidyl hexyl ether;2-(hexoxymethyl)oxirane;5926-90-9;2,3-Epoxypropylhexyl ether;Oxirane, ((hexyloxy)methyl)-;((Hexyloxy)methyl)oxirane;Propane, 1,2-epoxy-3-(hexyloxy)-;CCRIS 2633;EINECS 227-662-5;NSC 83416;UNII-0V30H1KF4J;0V30H1KF4J;NSC-83416;[(hexyloxy)methyl]oxirane;Oxirane, [(hexyloxy)methyl]-;hexylglycidyl ether;glycidylhexyl ether;1-hexyl glycidyl ether;1-hexanol glycidyl ether;NCIOpen2_001133;2-[(Hexyloxy)methyl]oxirane;GLYCIDYL N-HEXYL ETHER;SCHEMBL122128;2-[(Hexyloxy)methyl]oxirane #;DTXSID9025405;NSC83416;AKOS009075739;Oxirane, ((hexyloxy)methyl)- (9CI);LS-1416;1-(HEXYLOXY)-2,3-EPOXYPROPANE;OXIRANE, 2-((HEXYLOXY)METHYL)-;FT-0695404;Q27237284

Chemical Property of Hexyl glycidyl ether

Chemical Property:

• Vapor Pressure: 0.321mmHg at 25°C
• Refractive Index: 1.4350 (estimate)
• Boiling Point: 207.6°C at 760 mmHg
• Flash Point: 80.2°C
• PSA: 21.76000
• Density: 0.926g/cm³
• LogP: 1.98210
• XLogP3: 2.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 7
• Exact Mass: 158.130679813
• Heavy Atom Count: 11
• Complexity: 93.6

Purity/Quality:

99% ^*data from raw suppliers

[(HEXYLOXY)METHYL]OXIRANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCOCC1CO1

Technology Process of Hexyl glycidyl ether

There total 7 articles about Hexyl glycidyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

Glycidyl 5-hexenyl ether → hexyloxymethyloxirane (5926-90-9)

Guidance literature:

With hydrogen; 5percent Pd/C(en); In tetrahydrofuran; at 20 ℃; for 3h;

DOI:10.1002/1521-3765(20000616)6:12<2200::AID-CHEM2200>3.0.CO;2-3

Reference yield: 52.0%

epichlorohydrin (106-89-8,24969-06-0,13403-37-7) + hexan-1-ol (111-27-3) → hexyloxymethyloxirane (5926-90-9)

Guidance literature:

With tetra-(n-butyl)ammonium iodide; sodium hydroxide; In water; benzene;

DOI:10.1134/S1070363214110139

Reference yield:

5-Hexen-1-ol (821-41-0) → hexyloxymethyloxirane (5926-90-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 75 percent / tetrabutylammonium hydrogensulfate; aq. NaOH / 9 h / 20 °C

2: 92 percent / H₂ / 5percent Pd/C(en) / tetrahydrofuran / 3 h / 20 °C

With sodium hydroxide; hydrogen; tetra(n-butyl)ammonium hydrogensulfate; 5percent Pd/C(en); In tetrahydrofuran; 1: Etherification / 2: Catalytic hydrogenation;

DOI:10.1002/1521-3765(20000616)6:12<2200::AID-CHEM2200>3.0.CO;2-3

upstream raw materials:

1-chloro-3-hexyloxy-propan-2-ol

epichlorohydrin

hexan-1-ol

5-Hexen-1-ol

Downstream raw materials:

hexyl glycerol

N-(2-Hydroxy-3-hexanoxypropyl)-1,1-dimethyl-2-(4-methoxyphenyl)ethylamine

hexyl 2-propenyl ether

hexan-1-ol

Refernces

• 1、 Sajiki, Hironao,Hattori, Kazuyuki,Hirota, Kosaku. "Highly chemoselective hydrogenation with retention of the epoxide function using a heterogeneous Pd/C - Ethylenediamine catalyst and THF". . p. 2200 - 2204. Retrieved 2007/10/03.
• 2、 Gloe, K.,Muehl, P.,Beger, J.,Poeschmann, C.,Petrich, M.,Beyer, L.. "Liquid-Liquid-Extraction of Metal Ions with Lariat Ethers". . p. 413 - 421. Retrieved 2007/10/02.